Varying the regiochemistry of a [2 + 2] cycloaddition reaction within isostructural hydrogen bonded cocrystals containing 4-stilbazole

Anna L. Grobelny; Nigam Rath; Ryan H. Groeneman

doi:10.1039/C8CE00447A

Varying the regiochemistry of a [2 + 2] cycloaddition reaction within isostructural hydrogen bonded cocrystals containing 4-stilbazole

Anna L. Grobelny, Nigam Rath, Ryan H. Groeneman

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

Cocrystallization of 4-stilbazole with 4,6-diX resorcinol (X = Cl or Br) yields a pair of photoreactive isostructural solids . Small variations in the spatial arrangement within each cocrystal leads to either the head-to-head (hh) or the unexpected head-to-tail (ht) photoproduct after undergoing a solid-state [2 + 2] cycloaddition reaction.

Original language	American English
Journal	CrystEngComm
Volume	20
DOIs	https://doi.org/10.1039/C8CE00447A
State	Published - Jun 8 2018

Disciplines

Biochemical and Biomolecular Engineering
Biochemistry, Biophysics, and Structural Biology
Biochemistry

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10.1039/C8CE00447ALicense: Unspecified

Cite this

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title = "Varying the regiochemistry of a [2 + 2] cycloaddition reaction within isostructural hydrogen bonded cocrystals containing 4-stilbazole",

abstract = " Cocrystallization of 4-stilbazole with 4,6-diX resorcinol (X = Cl or Br) yields a pair of photoreactive isostructural solids . Small variations in the spatial arrangement within each cocrystal leads to either the head-to-head (hh) or the unexpected head-to-tail (ht) photoproduct after undergoing a solid-state [2 + 2] cycloaddition reaction. ",

author = "Grobelny, {Anna L.} and Nigam Rath and Groeneman, {Ryan H.}",

note = "Cocrystallization of 4-stilbazole with 4,6-diX resorcinol (X = Cl or Br) yields a pair of photoreactive isostructural solids. Small variations in the spatial arrangement within each cocrystal leads to either the head-to-head (hh) or the unexpected head-to-tail (ht) photoproduct after undergoing a solid-state",

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AU - Grobelny, Anna L.

AU - Rath, Nigam

AU - Groeneman, Ryan H.

N1 - Cocrystallization of 4-stilbazole with 4,6-diX resorcinol (X = Cl or Br) yields a pair of photoreactive isostructural solids. Small variations in the spatial arrangement within each cocrystal leads to either the head-to-head (hh) or the unexpected head-to-tail (ht) photoproduct after undergoing a solid-state

PY - 2018/6/8

Y1 - 2018/6/8

N2 - Cocrystallization of 4-stilbazole with 4,6-diX resorcinol (X = Cl or Br) yields a pair of photoreactive isostructural solids . Small variations in the spatial arrangement within each cocrystal leads to either the head-to-head (hh) or the unexpected head-to-tail (ht) photoproduct after undergoing a solid-state [2 + 2] cycloaddition reaction.

AB - Cocrystallization of 4-stilbazole with 4,6-diX resorcinol (X = Cl or Br) yields a pair of photoreactive isostructural solids . Small variations in the spatial arrangement within each cocrystal leads to either the head-to-head (hh) or the unexpected head-to-tail (ht) photoproduct after undergoing a solid-state [2 + 2] cycloaddition reaction.

UR - https://doi.org/10.1039/C8CE00447A

U2 - 10.1039/C8CE00447A

DO - 10.1039/C8CE00447A

M3 - Article

VL - 20

JO - CrystEngComm

JF - CrystEngComm

ER -

Varying the regiochemistry of a [2 + 2] cycloaddition reaction within isostructural hydrogen bonded cocrystals containing 4-stilbazole

Abstract

Disciplines

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