Vapor pressures and vaporization enthalpy of codlemone by correlation gas chromatography

Shannon M. Schultz; Harold H. Harris; James S. Chickos

doi:10.1016/j.jct.2015.06.002

Vapor pressures and vaporization enthalpy of codlemone by correlation gas chromatography

Shannon M. Schultz, Harold H. Harris, James S. Chickos

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

The vapor pressure and vaporization enthalpy of codlemone ( trans , trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated by correlation gas chromatography using a series of saturated primary alcohols as standards. A vaporization enthalpy of (92.3 ± 2.6) kJ · mol −1 and a vapor pressure, p /Pa = (0.083 ± 0.012) were evaluated at T = 298.15 K. An equation for the evaluation of vapor pressure from ambient temperature to boiling has been derived by correlation for codlemone. The calculated boiling temperature of T B = 389 K at p = 267 Pa is within the temperature range reported in the literature. A normal boiling temperature of T B = (549.1 ± 0.1) K is also estimated by extrapolation.

Original language	American English
Journal	The Journal of Chemical Thermodynamics
Volume	89
DOIs	https://doi.org/10.1016/j.jct.2015.06.002
State	Published - Jan 10 2015

Keywords

10-Dodecadien-1-ol
Boiling temperature
Codlemone
Correlation gas chromatography
Vapor pressure vaporization enthalpy
trans
trans 8

Disciplines

Analytical Chemistry
Inorganic Chemistry

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10.1016/j.jct.2015.06.002License: Unspecified

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@article{003976660a224e5fa23201b4716b4863,

title = "Vapor pressures and vaporization enthalpy of codlemone by correlation gas chromatography",

abstract = " The vapor pressure and vaporization enthalpy of codlemone ( trans , trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated by correlation gas chromatography using a series of saturated primary alcohols as standards. A vaporization enthalpy of (92.3 ± 2.6) kJ · mol −1 and a vapor pressure, p /Pa = (0.083 ± 0.012) were evaluated at T = 298.15 K. An equation for the evaluation of vapor pressure from ambient temperature to boiling has been derived by correlation for codlemone. The calculated boiling temperature of T B = 389 K at p = 267 Pa is within the temperature range reported in the literature. A normal boiling temperature of T B = (549.1 ± 0.1) K is also estimated by extrapolation. ",

keywords = "10-Dodecadien-1-ol, Boiling temperature, Codlemone, Correlation gas chromatography, Vapor pressure vaporization enthalpy, trans, trans 8",

author = "Schultz, \{Shannon M.\} and Harris, \{Harold H.\} and Chickos, \{James S.\}",

note = "The vapor pressure and vaporization enthalpy of codlemone (trans, trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated...",

year = "2015",

month = jan,

day = "10",

doi = "10.1016/j.jct.2015.06.002",

language = "American English",

volume = "89",

journal = "The Journal of Chemical Thermodynamics",

}

TY - JOUR

T1 - Vapor pressures and vaporization enthalpy of codlemone by correlation gas chromatography

AU - Schultz, Shannon M.

AU - Harris, Harold H.

AU - Chickos, James S.

N1 - The vapor pressure and vaporization enthalpy of codlemone (trans, trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated...

PY - 2015/1/10

Y1 - 2015/1/10

N2 - The vapor pressure and vaporization enthalpy of codlemone ( trans , trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated by correlation gas chromatography using a series of saturated primary alcohols as standards. A vaporization enthalpy of (92.3 ± 2.6) kJ · mol −1 and a vapor pressure, p /Pa = (0.083 ± 0.012) were evaluated at T = 298.15 K. An equation for the evaluation of vapor pressure from ambient temperature to boiling has been derived by correlation for codlemone. The calculated boiling temperature of T B = 389 K at p = 267 Pa is within the temperature range reported in the literature. A normal boiling temperature of T B = (549.1 ± 0.1) K is also estimated by extrapolation.

AB - The vapor pressure and vaporization enthalpy of codlemone ( trans , trans 8,10-dodecadien-1-ol), the female sex hormone of the codling moth is evaluated by correlation gas chromatography using a series of saturated primary alcohols as standards. A vaporization enthalpy of (92.3 ± 2.6) kJ · mol −1 and a vapor pressure, p /Pa = (0.083 ± 0.012) were evaluated at T = 298.15 K. An equation for the evaluation of vapor pressure from ambient temperature to boiling has been derived by correlation for codlemone. The calculated boiling temperature of T B = 389 K at p = 267 Pa is within the temperature range reported in the literature. A normal boiling temperature of T B = (549.1 ± 0.1) K is also estimated by extrapolation.

KW - 10-Dodecadien-1-ol

KW - Boiling temperature

KW - Codlemone

KW - Correlation gas chromatography

KW - Vapor pressure vaporization enthalpy

KW - trans

KW - trans 8

UR - https://www.sciencedirect.com/science/article/pii/S0021961415001780

U2 - 10.1016/j.jct.2015.06.002

DO - 10.1016/j.jct.2015.06.002

M3 - Article

VL - 89

JO - The Journal of Chemical Thermodynamics

JF - The Journal of Chemical Thermodynamics

ER -

Vapor pressures and vaporization enthalpy of codlemone by correlation gas chromatography

Abstract

Keywords

Disciplines

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