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Thermophysical Study of Several Barbituric Acid Derivatives by Differential Scanning Calorimetry (DSC)

  • Manuel Temprado
  • , María Victoria Roux
  • , Francisco Ros
  • , Rafael Notario
  • , Marta Segura
  • , James S. Chickos

Research output: Contribution to journalArticlepeer-review

Abstract

The present study reports a differential scanning calorimetry (DSC) study of the barbituric acid derivatives: 1,3-dimethylbarbituric acid [CAS 769-42-6], 5,5-dimethylbarbituric acid [CAS 24448-94-0], 1,3-diethylbarbituric acid [CAS 32479-73-5], 1,3,5-trimethylbarbituric acid [CAS 7358-61-4], 1,5,5-trimethylbarbituric acid [CAS 702-47-6], and tetramethylbarbituric acid [CAS 13566-66-0] in the temperature interval from  T  = 268 K to their respective melting temperatures. Temperatures, enthalpies and entropies of fusion, and the heat capacities of the solid compounds as a function of temperature are reported.
Original languageAmerican English
JournalJournal of Chemical & Engineering Data
Volume56
DOIs
StatePublished - Feb 10 2011

Keywords

  • Differential scanning calorimetry
  • Entropy
  • Heat capacity
  • Phase transitions
  • Reaction products

Disciplines

  • Inorganic Chemistry

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