Thermolysis of (1R,2R)-1,2-dideuteriocyclobutane. An application of vibrational circular dichroism to kinetic analysis

James S. Chickos; A. Annamalai; T. A. Keiderling

doi:10.1021/ja00275a028

Thermolysis of (1R,2R)-1,2-dideuteriocyclobutane. An application of vibrational circular dichroism to kinetic analysis

James S. Chickos
, A. Annamalai
, T. A. Keiderling

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of the American Chemical Society
Volume	108
DOIs	https://doi.org/10.1021/ja00275a028
State	Published - Jan 7 1986

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Organic Chemistry

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@article{8a990c516eb34c0dacc013aab65943c9,

title = "Thermolysis of (1R,2R)-1,2-dideuteriocyclobutane. An application of vibrational circular dichroism to kinetic analysis",

author = "Chickos, \{James S.\} and A. Annamalai and Keiderling, \{T. A.\}",

note = "AB - The relative rates of geometric isomerization to racemization have been studied for the title compound by using a combination of infrared (IR) and vibrational circular dichroism (VCD) spectroscopies, respectively. The results are interpreted with a kinetic and mechanistic scheme which parallels that used by Berson, Pedersen, and Carpenter on a similar study of chiral cyclopropane-d2 thermolysis.",

year = "1986",

month = jan,

day = "7",

doi = "10.1021/ja00275a028",

language = "American English",

volume = "108",

journal = "Journal of the American Chemical Society",

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TY - JOUR

T1 - Thermolysis of (1R,2R)-1,2-dideuteriocyclobutane. An application of vibrational circular dichroism to kinetic analysis

AU - Chickos, James S.

AU - Annamalai, A.

AU - Keiderling, T. A.

N1 - AB - The relative rates of geometric isomerization to racemization have been studied for the title compound by using a combination of infrared (IR) and vibrational circular dichroism (VCD) spectroscopies, respectively. The results are interpreted with a kinetic and mechanistic scheme which parallels that used by Berson, Pedersen, and Carpenter on a similar study of chiral cyclopropane-d2 thermolysis.

PY - 1986/1/7

Y1 - 1986/1/7

UR - https://iwe.pure.elsevier.com/en/publications/thermolysis-of-1r2r-12-dideuteriocyclobutane-an-application-of-vi

U2 - 10.1021/ja00275a028

DO - 10.1021/ja00275a028

M3 - Article

VL - 108

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Thermolysis of (1R,2R)-1,2-dideuteriocyclobutane. An application of vibrational circular dichroism to kinetic analysis

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