Thermolysis of (1R,2R)-1,2-dideuteriocyclobutane. An application of vibrational circular dichroism to kinetic analysis

TY - JOUR

T1 - Thermolysis of (1R,2R)-1,2-dideuteriocyclobutane. An application of vibrational circular dichroism to kinetic analysis

AU - Chickos, James S.

AU - Annamalai, A.

AU - Keiderling, T. A.

N1 - AB - The relative rates of geometric isomerization to racemization have been studied for the title compound by using a combination of infrared (IR) and vibrational circular dichroism (VCD) spectroscopies, respectively. The results are interpreted with a kinetic and mechanistic scheme which parallels that used by Berson, Pedersen, and Carpenter on a similar study of chiral cyclopropane-d2 thermolysis.

PY - 1986/1/7

Y1 - 1986/1/7

UR - https://iwe.pure.elsevier.com/en/publications/thermolysis-of-1r2r-12-dideuteriocyclobutane-an-application-of-vi

U2 - 10.1021/ja00275a028

DO - 10.1021/ja00275a028

M3 - Article

VL - 108

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -