Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature

Yuan-Zhu Zhang; Philip Ferko; Diana Siretanu; Rodica Ababei; Nigam P. Rath; Michael J. Shaw; Rodolphe Clérac; Corine Mathonière; Stephen M. Holmes

doi:10.1021/ja508280n

Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature

Yuan-Zhu Zhang, Philip Ferko, Diana Siretanu, Rodica Ababei, Nigam P. Rath, Michael J. Shaw, Rodolphe Clérac, Corine Mathonière, Stephen M. Holmes

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of the American Chemical Society
Volume	136
DOIs	https://doi.org/10.1021/ja508280n
State	Published - Dec 3 2014

Disciplines

Organic Chemistry
Inorganic Chemistry

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@article{823a7d61e1a043bd8b356d92b6a49a0b,

title = "Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature",

author = "Yuan-Zhu Zhang and Philip Ferko and Diana Siretanu and Rodica Ababei and Rath, \{Nigam P.\} and Shaw, \{Michael J.\} and Rodolphe Cl{\'e}rac and Corine Mathoni{\`e}re and Holmes, \{Stephen M.\}",

note = "Abstract : Two structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, \{Fe2Co2\}, are reported: \{[(TpMe)Fe(CN)3]2[Co(bpy)2]2[(TpMe)Fe- (CN)3]2\}·12H2O (2) and \{[(TpMe)Fe(CN)3]2[Co-(bpy)2]2[BPh4]2\}·6MeCN (3), where TpMe and bpy are hydridotris(3-methylpyrazol-1-yl)borate and 2,2′-bipyridine, respectively.....",

year = "2014",

month = dec,

day = "3",

doi = "10.1021/ja508280n",

language = "American English",

volume = "136",

journal = "Journal of the American Chemical Society",

}

TY - JOUR

T1 - Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature

AU - Zhang, Yuan-Zhu

AU - Ferko, Philip

AU - Siretanu, Diana

AU - Ababei, Rodica

AU - Rath, Nigam P.

AU - Shaw, Michael J.

AU - Clérac, Rodolphe

AU - Mathonière, Corine

AU - Holmes, Stephen M.

N1 - Abstract : Two structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, {Fe2Co2}, are reported: {[(TpMe)Fe(CN)3]2[Co(bpy)2]2[(TpMe)Fe- (CN)3]2}·12H2O (2) and {[(TpMe)Fe(CN)3]2[Co-(bpy)2]2[BPh4]2}·6MeCN (3), where TpMe and bpy are hydridotris(3-methylpyrazol-1-yl)borate and 2,2′-bipyridine, respectively.....

PY - 2014/12/3

Y1 - 2014/12/3

UR - https://pubs.acs.org/doi/full/10.1021/ja508280n

UR - https://hal.archives-ouvertes.fr/hal-01092286

U2 - 10.1021/ja508280n

DO - 10.1021/ja508280n

M3 - Article

VL - 136

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Thermochromic and Photoresponsive Cyanometalate Fe/Co Squares: Toward Control of the Electron Transfer Temperature

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