The Enantioselective Addition of Dialkylphosphites to Aldehydes: Catalysis by a Lanthanum Binaphthoxide Complex

Nigam Rath; Christopher D. Spilling

doi:10.1016/S0040-4039(00)76517-8

The Enantioselective Addition of Dialkylphosphites to Aldehydes: Catalysis by a Lanthanum Binaphthoxide Complex

Nigam Rath, Christopher D. Spilling

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

<div class="line" id="line-11"> The enantioselective addition of dialkylphosphites to aldehydes was catalyzed by a lanthanum ( <i> R </i> )-binaphthoxide complex to give ( <i> S </i> )-hydroxy phosphonates in good yield and modest enantioselectivity.</div><div class="line" id="line-39"> <img src="https://ars.els-cdn.com/content/image/1-s2.0-S0040403900765178-gr1.gif"/></div><div class="line" id="line-42"> <br/></div>

Original language	American English
Journal	Tetrahedron Letters
Volume	35
DOIs	https://doi.org/10.1016/S0040-4039(00)76517-8
State	Published - Jan 10 1994

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Chemistry

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title = "The Enantioselective Addition of Dialkylphosphites to Aldehydes: Catalysis by a Lanthanum Binaphthoxide Complex",

abstract = " The enantioselective addition of dialkylphosphites to aldehydes was catalyzed by a lanthanum ( R )-binaphthoxide complex to give ( S )-hydroxy phosphonates in good yield and modest enantioselectivity. ",

author = "Nigam Rath and Spilling, {Christopher D.}",

note = "The enantioselective addition of dialkylphosphites to aldehydes was catalyzed by a lanthanum (R)-binaphthoxide complex to give (S)-hydroxy phosphonate...",

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AU - Rath, Nigam

AU - Spilling, Christopher D.

N1 - The enantioselective addition of dialkylphosphites to aldehydes was catalyzed by a lanthanum (R)-binaphthoxide complex to give (S)-hydroxy phosphonate...

PY - 1994/1/10

Y1 - 1994/1/10

N2 - The enantioselective addition of dialkylphosphites to aldehydes was catalyzed by a lanthanum ( R )-binaphthoxide complex to give ( S )-hydroxy phosphonates in good yield and modest enantioselectivity.

AB - The enantioselective addition of dialkylphosphites to aldehydes was catalyzed by a lanthanum ( R )-binaphthoxide complex to give ( S )-hydroxy phosphonates in good yield and modest enantioselectivity.

UR - https://www.sciencedirect.com/science/article/pii/S0040403900765178

U2 - 10.1016/S0040-4039(00)76517-8

DO - 10.1016/S0040-4039(00)76517-8

M3 - Article

VL - 35

JO - Tetrahedron Letters

JF - Tetrahedron Letters

ER -

The Enantioselective Addition of Dialkylphosphites to Aldehydes: Catalysis by a Lanthanum Binaphthoxide Complex

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