Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†

UmaShanker Sampath; William C. Putnam; Todd A. Osiek; Sofia Touami; Jin Xie; Daniel Cohen; Aldo Cagnolini; Patricia Droege; David Klug; Charles L. Barnes; Anil Modak; James K. Bashkin; Silvia S. Jurisson

doi:10.1039/A808557I

Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†

UmaShanker Sampath
, William C. Putnam
, Todd A. Osiek
, Sofia Touami
, Jin Xie
, Daniel Cohen
, Aldo Cagnolini
, Patricia Droege
, David Klug
, Charles L. Barnes
, Anil Modak
, James K. Bashkin
, Silvia S. Jurisson

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of The Chemical Society-dalton Transactions
DOIs	https://doi.org/10.1039/A808557I
State	Published - Jan 1 1999

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Organic Chemistry
Inorganic Chemistry

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Sampath, U., Putnam, W. C., Osiek, T. A., Touami, S., Xie, J., Cohen, D., Cagnolini, A., Droege, P., Klug, D., Barnes, C. L., Modak, A., Bashkin, J. K., & Jurisson, S. S. (1999). Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†. Journal of The Chemical Society-dalton Transactions. https://doi.org/10.1039/A808557I

Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†. / Sampath, UmaShanker; Putnam, William C.; Osiek, Todd A. et al.
In: Journal of The Chemical Society-dalton Transactions, 01.01.1999.

Research output: Contribution to journal › Article › peer-review

Sampath, U, Putnam, WC, Osiek, TA, Touami, S, Xie, J, Cohen, D, Cagnolini, A, Droege, P, Klug, D, Barnes, CL, Modak, A, Bashkin, JK & Jurisson, SS 1999, 'Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†', Journal of The Chemical Society-dalton Transactions. https://doi.org/10.1039/A808557I

Sampath U, Putnam WC, Osiek TA, Touami S, Xie J, Cohen D et al. Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†. Journal of The Chemical Society-dalton Transactions. 1999 Jan 1. doi: 10.1039/A808557I

Sampath, UmaShanker ; Putnam, William C. ; Osiek, Todd A. et al. / Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†. In: Journal of The Chemical Society-dalton Transactions. 1999.

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title = "Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†",

author = "UmaShanker Sampath and Putnam, \{William C.\} and Osiek, \{Todd A.\} and Sofia Touami and Jin Xie and Daniel Cohen and Aldo Cagnolini and Patricia Droege and David Klug and Barnes, \{Charles L.\} and Anil Modak and Bashkin, \{James K.\} and Jurisson, \{Silvia S.\}",

note = "A variety of 2,2′∶6′,2″-terpyridine (terpy) derivatives modified at the 4′ position has been synthesized to generate bifunctional chelates. A particularly convenient route to these bifunctional chelates, based on nucleophilic substitution of 4′-chloroterpyridine is described. The crystal structure of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine has been determined.",

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T1 - Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†

AU - Sampath, UmaShanker

AU - Putnam, William C.

AU - Osiek, Todd A.

AU - Touami, Sofia

AU - Xie, Jin

AU - Cohen, Daniel

AU - Cagnolini, Aldo

AU - Droege, Patricia

AU - Klug, David

AU - Barnes, Charles L.

AU - Modak, Anil

AU - Bashkin, James K.

AU - Jurisson, Silvia S.

N1 - A variety of 2,2′∶6′,2″-terpyridine (terpy) derivatives modified at the 4′ position has been synthesized to generate bifunctional chelates. A particularly convenient route to these bifunctional chelates, based on nucleophilic substitution of 4′-chloroterpyridine is described. The crystal structure of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine has been determined.

PY - 1999/1/1

Y1 - 1999/1/1

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U2 - 10.1039/A808557I

DO - 10.1039/A808557I

M3 - Article

JO - Journal of The Chemical Society-dalton Transactions

JF - Journal of The Chemical Society-dalton Transactions

ER -

Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†

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