Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†

UmaShanker Sampath; William C. Putnam; Todd A. Osiek; Sofia Touami; Jin Xie; Daniel Cohen; Aldo Cagnolini; Patricia Droege; David Klug; Charles L. Barnes; Anil Modak; James K. Bashkin; Silvia S. Jurisson

doi:10.1039/A808557I

Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†

UmaShanker Sampath, William C. Putnam, Todd A. Osiek, Sofia Touami, Jin Xie, Daniel Cohen, Aldo Cagnolini, Patricia Droege, David Klug, Charles L. Barnes, Anil Modak, James K. Bashkin, Silvia S. Jurisson

University of Missouri-St. Louis

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Original language	American English
Journal	Journal of The Chemical Society-dalton Transactions
DOIs	https://doi.org/10.1039/A808557I
State	Published - Jan 1 1999

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Organic Chemistry
Inorganic Chemistry

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Sampath, U., Putnam, W. C., Osiek, T. A., Touami, S., Xie, J., Cohen, D., Cagnolini, A., Droege, P., Klug, D., Barnes, C. L., Modak, A., Bashkin, J. K., & Jurisson, S. S. (1999). Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†. Journal of The Chemical Society-dalton Transactions. https://doi.org/10.1039/A808557I

Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†. / Sampath, UmaShanker; Putnam, William C.; Osiek, Todd A. et al.
In: Journal of The Chemical Society-dalton Transactions, 01.01.1999.

Research output: Contribution to journal › Article › peer-review

Sampath, U, Putnam, WC, Osiek, TA, Touami, S, Xie, J, Cohen, D, Cagnolini, A, Droege, P, Klug, D, Barnes, CL, Modak, A, Bashkin, JK & Jurisson, SS 1999, 'Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†', Journal of The Chemical Society-dalton Transactions. https://doi.org/10.1039/A808557I

Sampath U, Putnam WC, Osiek TA, Touami S, Xie J, Cohen D et al. Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†. Journal of The Chemical Society-dalton Transactions. 1999 Jan 1. doi: 10.1039/A808557I

Sampath, UmaShanker ; Putnam, William C. ; Osiek, Todd A. et al. / Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†. In: Journal of The Chemical Society-dalton Transactions. 1999.

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title = "Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†",

author = "UmaShanker Sampath and Putnam, {William C.} and Osiek, {Todd A.} and Sofia Touami and Jin Xie and Daniel Cohen and Aldo Cagnolini and Patricia Droege and David Klug and Barnes, {Charles L.} and Anil Modak and Bashkin, {James K.} and Jurisson, {Silvia S.}",

note = "A variety of 2,2′∶6′,2″-terpyridine (terpy) derivatives modified at the 4′ position has been synthesized to generate bifunctional chelates. A particularly convenient route to these bifunctional chelates, based on nucleophilic substitution of 4′-chloroterpyridine is described. The crystal structure of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine has been determined.",

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T1 - Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†

AU - Sampath, UmaShanker

AU - Putnam, William C.

AU - Osiek, Todd A.

AU - Touami, Sofia

AU - Xie, Jin

AU - Cohen, Daniel

AU - Cagnolini, Aldo

AU - Droege, Patricia

AU - Klug, David

AU - Barnes, Charles L.

AU - Modak, Anil

AU - Bashkin, James K.

AU - Jurisson, Silvia S.

N1 - A variety of 2,2′∶6′,2″-terpyridine (terpy) derivatives modified at the 4′ position has been synthesized to generate bifunctional chelates. A particularly convenient route to these bifunctional chelates, based on nucleophilic substitution of 4′-chloroterpyridine is described. The crystal structure of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine has been determined.

PY - 1999/1/1

Y1 - 1999/1/1

UR - http://pubs.rsc.org/en/Content/ArticleLanding/DT/1999/A808557I#!

U2 - 10.1039/A808557I

DO - 10.1039/A808557I

M3 - Article

JO - Journal of The Chemical Society-dalton Transactions

JF - Journal of The Chemical Society-dalton Transactions

ER -

Terpyridyl derivatives as bifunctional chelates: synthesis and crystal structures of 4′-[2-(1,3-dioxolan-2-yl)ethylsulfanyl]-2,2′∶6′,2″-terpyridine and chloro(4′-methylsulfanyl-2,2′∶6′,2″-terpyridine)gold(III) bis(trifluoromethanesulfonate)†

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