Synthesis, Structure, and Spectroscopy of Silaallyl− and Silapentadienyl−Iridium−Phosphine Complexes

John R. Bleeke; Todsapon Thananatthanachon; Nigam Rath

doi:10.1021/om700487n

Synthesis, Structure, and Spectroscopy of Silaallyl− and Silapentadienyl−Iridium−Phosphine Complexes

John R. Bleeke, Todsapon Thananatthanachon, Nigam Rath

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

<div class="line" id="line-11"> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 17px;"> Silaallyl− and silapentadienyl−iridium−phosphine complexes have been synthesized via the reaction of “(Me)Ir(PMe </span> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 12.75px;"> 3 </span> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 17px;"> ) </span> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 12.75px;"> 3 </span> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 17px;"> ” with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C−H bond activation to produce a five-membered iridasilacycle, C </span> <img src="https://pubs.acs.org/entityImage/legacy/dbd.gif"/> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 17px;"> C bond coordination to generate an η </span> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 12.75px;"> 1 </span> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 17px;"> ,η </span> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 12.75px;"> 2 </span> <span style="background-color: rgb(244, 244, 244); font-family: Georgia, serif; font-size: 17px;"> -silapentadienyl ligand, and decomposition. </span></div><div class="line" id="line-25"> <br/></div><div class="line" id="line-28"> Link to correction: <a href="https://doi.org/10.1021/om800116g"> <span style="font-family: Roboto, arial, sans-serif; font-size: 12px;"> https://doi.org/10.1021/om800116g </span> </a></div>

Original language	American English
Journal	Organometallics
Volume	26
DOIs	https://doi.org/10.1021/om700487n
State	Published - Jun 30 2007

Keywords

Alkyls
Group 15 compounds
Hydrocarbons
Ligands
Mathematical methods

Disciplines

Life Sciences
Biochemistry, Biophysics, and Structural Biology
Biochemistry

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title = "Synthesis, Structure, and Spectroscopy of Silaallyl− and Silapentadienyl−Iridium−Phosphine Complexes",

abstract = " Silaallyl− and silapentadienyl−iridium−phosphine complexes have been synthesized via the reaction of “(Me)Ir(PMe 3 ) 3 ” with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C−H bond activation to produce a five-membered iridasilacycle, C C bond coordination to generate an η 1 ,η 2 -silapentadienyl ligand, and decomposition. Link to correction: https://doi.org/10.1021/om800116g ",

keywords = "Alkyls, Group 15 compounds, Hydrocarbons, Ligands, Mathematical methods",

author = "Bleeke, {John R.} and Todsapon Thananatthanachon and Nigam Rath",

note = "Silaallyl− and silapentadienyl−iridium−phosphine complexes have been synthesized via the reaction of {"}(Me)Ir(PMe3)3{"} with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C−H bond activation to produce a five-membered iridasilacycle, CC bond coordination to generate an η1,η2-silapentadienyl ligand, and decomposition.",

year = "2007",

month = jun,

day = "30",

doi = "10.1021/om700487n",

language = "American English",

volume = "26",

journal = "Organometallics",

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TY - JOUR

T1 - Synthesis, Structure, and Spectroscopy of Silaallyl− and Silapentadienyl−Iridium−Phosphine Complexes

AU - Bleeke, John R.

AU - Thananatthanachon, Todsapon

AU - Rath, Nigam

N1 - Silaallyl− and silapentadienyl−iridium−phosphine complexes have been synthesized via the reaction of "(Me)Ir(PMe3)3" with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C−H bond activation to produce a five-membered iridasilacycle, CC bond coordination to generate an η1,η2-silapentadienyl ligand, and decomposition.

PY - 2007/6/30

Y1 - 2007/6/30

N2 - Silaallyl− and silapentadienyl−iridium−phosphine complexes have been synthesized via the reaction of “(Me)Ir(PMe 3 ) 3 ” with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C−H bond activation to produce a five-membered iridasilacycle, C C bond coordination to generate an η 1 ,η 2 -silapentadienyl ligand, and decomposition. Link to correction: https://doi.org/10.1021/om800116g

AB - Silaallyl− and silapentadienyl−iridium−phosphine complexes have been synthesized via the reaction of “(Me)Ir(PMe 3 ) 3 ” with vinyl- and butadienyldimethylsilanes. Upon heating, these complexes lose methane and undergo a variety of reactions, including C−H bond activation to produce a five-membered iridasilacycle, C C bond coordination to generate an η 1 ,η 2 -silapentadienyl ligand, and decomposition. Link to correction: https://doi.org/10.1021/om800116g

KW - Alkyls

KW - Group 15 compounds

KW - Hydrocarbons

KW - Ligands

KW - Mathematical methods

UR - https://doi.org/10.1021/om700487n

U2 - 10.1021/om700487n

DO - 10.1021/om700487n

M3 - Article

VL - 26

JO - Organometallics

JF - Organometallics

ER -

Synthesis, Structure, and Spectroscopy of Silaallyl− and Silapentadienyl−Iridium−Phosphine Complexes

Abstract

Keywords

Disciplines

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