Synthesis, Structural Characterization and Catalytic Activity of Indenyl tris-N-Pyrrolyl Phosphine Complexes of Ruthenium

TY - JOUR

T1 - Synthesis, Structural Characterization and Catalytic Activity of Indenyl tris-N-Pyrrolyl Phosphine Complexes of Ruthenium

AU - Stark, Matthew J.

AU - Shaw, Michael J.

AU - Rath, Nigam P.

AU - Bauer, Eike B.

N1 - The synthesis, characterization and catalytic activity of new ruthenium complexes of the tris-N-pyrrolyl phosphine ligand P(pyr)3 is described. The new ruthenium complexes [RuCl(ind)(PPh3){P(pyr)3}] and [RuCl(ind){P(pyr)3}2] (ind = indenyl ligand η5-C9H7−) were synthesized in 73% and 63% isolated yield, respectively, by thermal ligand exchange of [RuCl(ind)(PPh3)2] with P(pyr)3.

PY - 2016/3/1

Y1 - 2016/3/1

UR - https://spark.siue.edu/siue_fac/30/

U2 - 10.1002/ejic.201501381

DO - 10.1002/ejic.201501381

M3 - Article

VL - 2016

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

ER -