Synthesis, Structural Characterization and Catalytic Activity of Indenyl tris-N-Pyrrolyl Phosphine Complexes of Ruthenium

Matthew J. Stark; Michael J. Shaw; Nigam P. Rath; Eike B. Bauer

doi:10.1002/ejic.201501381

Synthesis, Structural Characterization and Catalytic Activity of Indenyl tris-N-Pyrrolyl Phosphine Complexes of Ruthenium

Matthew J. Stark, Michael J. Shaw, Nigam P. Rath, Eike B. Bauer

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	European Journal of Inorganic Chemistry
Volume	2016
DOIs	https://doi.org/10.1002/ejic.201501381
State	Published - Mar 1 2016

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Chemistry
Inorganic Chemistry

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@article{8d1159ae685d406ba920152a2656c95c,

title = "Synthesis, Structural Characterization and Catalytic Activity of Indenyl tris-N-Pyrrolyl Phosphine Complexes of Ruthenium",

author = "Stark, {Matthew J.} and Shaw, {Michael J.} and Rath, {Nigam P.} and Bauer, {Eike B.}",

note = "The synthesis, characterization and catalytic activity of new ruthenium complexes of the tris-N-pyrrolyl phosphine ligand P(pyr)3 is described. The new ruthenium complexes [RuCl(ind)(PPh3){P(pyr)3}] and [RuCl(ind){P(pyr)3}2] (ind = indenyl ligand η5-C9H7−) were synthesized in 73% and 63% isolated yield, respectively, by thermal ligand exchange of [RuCl(ind)(PPh3)2] with P(pyr)3.",

year = "2016",

month = mar,

day = "1",

doi = "10.1002/ejic.201501381",

language = "American English",

volume = "2016",

journal = "European Journal of Inorganic Chemistry",

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TY - JOUR

T1 - Synthesis, Structural Characterization and Catalytic Activity of Indenyl tris-N-Pyrrolyl Phosphine Complexes of Ruthenium

AU - Stark, Matthew J.

AU - Shaw, Michael J.

AU - Rath, Nigam P.

AU - Bauer, Eike B.

N1 - The synthesis, characterization and catalytic activity of new ruthenium complexes of the tris-N-pyrrolyl phosphine ligand P(pyr)3 is described. The new ruthenium complexes [RuCl(ind)(PPh3){P(pyr)3}] and [RuCl(ind){P(pyr)3}2] (ind = indenyl ligand η5-C9H7−) were synthesized in 73% and 63% isolated yield, respectively, by thermal ligand exchange of [RuCl(ind)(PPh3)2] with P(pyr)3.

PY - 2016/3/1

Y1 - 2016/3/1

UR - https://spark.siue.edu/siue_fac/30/

U2 - 10.1002/ejic.201501381

DO - 10.1002/ejic.201501381

M3 - Article

VL - 2016

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

ER -

Synthesis, Structural Characterization and Catalytic Activity of Indenyl tris-N-Pyrrolyl Phosphine Complexes of Ruthenium

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