Synthesis, Spectroscopy, Structure, and Reactivity of Bis-Azapentadienyl–Ruthenium–Phosphine Complexes

John R. Bleeke; Meghan Stouffer; Nigam P. Rath

doi:10.1016/j.jorganchem.2015.01.006

Synthesis, Spectroscopy, Structure, and Reactivity of Bis-Azapentadienyl–Ruthenium–Phosphine Complexes

John R. Bleeke
, Meghan Stouffer
, Nigam P. Rath

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of Organometallic Chemistry
Volume	781
DOIs	https://doi.org/10.1016/j.jorganchem.2015.01.006
State	Published - Apr 1 2015

Disciplines

Chemistry
Inorganic Chemistry

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@article{443105a5f62d4b0696c718f0e2d46874,

title = "Synthesis, Spectroscopy, Structure, and Reactivity of Bis-Azapentadienyl–Ruthenium–Phosphine Complexes",

author = "Bleeke, \{John R.\} and Meghan Stouffer and Rath, \{Nigam P.\}",

note = "The first examples of bis-(η 3-azapentadienyl)RuL 2 complexes have been synthesized and characterized. * The complexes adopt a variety of structural motifs, which differ in the orientation of the azapentadienyl ligands. * Dynamic interconversions between these structural types are observed. * The azapentadienyl nitrogens are the preferred sites of electrophilic attack.",

year = "2015",

month = apr,

day = "1",

doi = "10.1016/j.jorganchem.2015.01.006",

language = "American English",

volume = "781",

journal = "Journal of Organometallic Chemistry",

}

TY - JOUR

T1 - Synthesis, Spectroscopy, Structure, and Reactivity of Bis-Azapentadienyl–Ruthenium–Phosphine Complexes

AU - Bleeke, John R.

AU - Stouffer, Meghan

AU - Rath, Nigam P.

N1 - The first examples of bis-(η 3-azapentadienyl)RuL 2 complexes have been synthesized and characterized. * The complexes adopt a variety of structural motifs, which differ in the orientation of the azapentadienyl ligands. * Dynamic interconversions between these structural types are observed. * The azapentadienyl nitrogens are the preferred sites of electrophilic attack.

PY - 2015/4/1

Y1 - 2015/4/1

UR - https://www.sciencedirect.com/science/article/pii/S0022328X15000200

U2 - 10.1016/j.jorganchem.2015.01.006

DO - 10.1016/j.jorganchem.2015.01.006

M3 - Article

VL - 781

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Synthesis, Spectroscopy, Structure, and Reactivity of Bis-Azapentadienyl–Ruthenium–Phosphine Complexes

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