Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex : Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes

Gurusamy Thangavelu Senthil Andavan; Eike B. Bauer; Christopher S. Letko; T. Keith Hollis; Fook S. Tham

doi:10.1016/j.jorganchem.2005.07.088

Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex : Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes

Gurusamy Thangavelu Senthil Andavan
, Eike B. Bauer
, Christopher S. Letko
, T. Keith Hollis
, Fook S. Tham

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of Organometallic Chemistry
Volume	690
DOIs	https://doi.org/10.1016/j.jorganchem.2005.07.088
State	Published - Jan 12 2005
Externally published	Yes

Disciplines

Chemistry
Organic Chemistry

Access to Document

10.1016/j.jorganchem.2005.07.088License: Unspecified

Cite this

Andavan, G. T. S., Bauer, E. B., Letko, C. S., Hollis, T. K., & Tham, F. S. (2005). Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex : Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes. Journal of Organometallic Chemistry, 690. https://doi.org/10.1016/j.jorganchem.2005.07.088

Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex : Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes. / Andavan, Gurusamy Thangavelu Senthil; Bauer, Eike B.; Letko, Christopher S. et al.
In: Journal of Organometallic Chemistry, Vol. 690, 12.01.2005.

Research output: Contribution to journal › Article › peer-review

Andavan, GTS, Bauer, EB, Letko, CS, Hollis, TK & Tham, FS 2005, 'Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex : Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes', Journal of Organometallic Chemistry, vol. 690. https://doi.org/10.1016/j.jorganchem.2005.07.088

@article{7cdfb9594eca464194e7f6e0b735f6ad,

title = "Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex : Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes",

author = "Andavan, \{Gurusamy Thangavelu Senthil\} and Bauer, \{Eike B.\} and Letko, \{Christopher S.\} and Hollis, \{T. Keith\} and Tham, \{Fook S.\}",

note = "JavaScript is disabled on your browser. Please enable JavaScript to use all the features on this page. 1,3-Bis(3-butylimidazolium-1-yl)benzene diiodide ( 1) was reacted with Li(2,2,6,6-tetramethylpiperidine) yielding the free bis-carbene, 1,3-bis(3-butylimidazol-2-ylidene-1-yl)benzene ( 3), which has been spectroscopically characterized. Combining the free bis-carbene with [Rh(COD)Cl] 2 yielded the corresponding di-Rh bis(N-heterocyclic carbene) complex ( 4) that was structurally characterized.",

year = "2005",

month = jan,

day = "12",

doi = "10.1016/j.jorganchem.2005.07.088",

language = "American English",

volume = "690",

journal = "Journal of Organometallic Chemistry",

}

TY - JOUR

T1 - Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex : Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes

AU - Andavan, Gurusamy Thangavelu Senthil

AU - Bauer, Eike B.

AU - Letko, Christopher S.

AU - Hollis, T. Keith

AU - Tham, Fook S.

N1 - JavaScript is disabled on your browser. Please enable JavaScript to use all the features on this page. 1,3-Bis(3-butylimidazolium-1-yl)benzene diiodide ( 1) was reacted with Li(2,2,6,6-tetramethylpiperidine) yielding the free bis-carbene, 1,3-bis(3-butylimidazol-2-ylidene-1-yl)benzene ( 3), which has been spectroscopically characterized. Combining the free bis-carbene with [Rh(COD)Cl] 2 yielded the corresponding di-Rh bis(N-heterocyclic carbene) complex ( 4) that was structurally characterized.

PY - 2005/1/12

Y1 - 2005/1/12

UR - https://www.sciencedirect.com/science/article/pii/S0022328X0500642X

U2 - 10.1016/j.jorganchem.2005.07.088

DO - 10.1016/j.jorganchem.2005.07.088

M3 - Article

VL - 690

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex : Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes

Disciplines

Access to Document

Other files and links

Cite this