Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp*)M^II(CN)2] [M^II = Cr, Co, Ni; Tp* = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]

Stephen Holmes; Dongfeng Li; Chad Ruschmann; Rodolphe Clérac

Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp)M^II(CN)2] [M^II = Cr, Co, Ni; Tp = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]

Stephen Holmes
, Dongfeng Li
, Chad Ruschmann
, Rodolphe Clérac

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Chemical Communications
State	Published - 2006

Disciplines

Physical Sciences and Mathematics

Cite this

@article{ed7614c9ce8f4ab69bd07782595c24d7,

title = "Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp*)M\textasciicircum{}II(CN)2] [M\textasciicircum{}II = Cr, Co, Ni; Tp* = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]",

author = "Stephen Holmes and Dongfeng Li and Chad Ruschmann and Rodolphe Cl{\'e}rac",

note = "The syntheses and structures of three dicyanometalate(ii) complexes, [NEt4][(Tp*)MII(CN)2]·nMeCN·½Et2O (MII = Cr, 1, n = ½; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and ½ complexes, respectively.",

year = "2006",

language = "American English",

journal = "Chemical Communications",

}

TY - JOUR

T1 - Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp*)M^II(CN)2] [M^II = Cr, Co, Ni; Tp* = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]

AU - Holmes, Stephen

AU - Li, Dongfeng

AU - Ruschmann, Chad

AU - Clérac, Rodolphe

N1 - The syntheses and structures of three dicyanometalate(ii) complexes, [NEt4][(Tp*)MII(CN)2]·nMeCN·½Et2O (MII = Cr, 1, n = ½; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and ½ complexes, respectively.

PY - 2006

Y1 - 2006

UR - https://pubs.rsc.org/en/Content/ArticleLanding/2006/CC/B608297A#!divAbstract

M3 - Article

JO - Chemical Communications

JF - Chemical Communications

ER -

Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp*)M^II(CN)2] [M^II = Cr, Co, Ni; Tp* = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]

Disciplines

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Cite this

Syntheses, Structures, and Magnetic Characterizatoin of Dicyanometalate(II) Building Blocks: [NEt4][(Tp)M^II(CN)2] [M^II = Cr, Co, Ni; Tp = Hydridotris(3,5-dimethylpyrazol-1-yl)borate]