Structural and Reactivity Comparison of Analogous Organometallic Pd(III) and Pd(IV) Complexes

Fengzhi Tang; Fengrui Qu; Julia R. Khusnutdinova; Nigam P. Rath; Liviu M. Mirica

doi:10.1039/c2dt32127k

Structural and Reactivity Comparison of Analogous Organometallic Pd(III) and Pd(IV) Complexes

Fengzhi Tang
, Fengrui Qu
, Julia R. Khusnutdinova
, Nigam P. Rath
, Liviu M. Mirica

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Dalton Transactions
Volume	41
DOIs	https://doi.org/10.1039/c2dt32127k
State	Published - Jan 1 2012

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Inorganic Chemistry
Chemistry

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@article{40ae089055df436a8195dfeadd9da9bf,

title = "Structural and Reactivity Comparison of Analogous Organometallic Pd(III) and Pd(IV) Complexes",

author = "Fengzhi Tang and Fengrui Qu and Khusnutdinova, \{Julia R.\} and Rath, \{Nigam P.\} and Mirica, \{Liviu M.\}",

note = "The tetradentate ligands RN4 (RN4 = N,N′-di-alkyl-2,11-diaza[3,3](2,6)pyridinophane, R = Me or iPr) were found to stabilize cationic (RN4)PdMe2 and (RN4)PdMeCl complexes in both PdIII and PdIV oxidation states. This allows for the first time a direct structural and reactivity comparison of the two Pd oxidati",

year = "2012",

month = jan,

day = "1",

doi = "10.1039/c2dt32127k",

language = "American English",

volume = "41",

journal = "Dalton Transactions",

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TY - JOUR

T1 - Structural and Reactivity Comparison of Analogous Organometallic Pd(III) and Pd(IV) Complexes

AU - Tang, Fengzhi

AU - Qu, Fengrui

AU - Khusnutdinova, Julia R.

AU - Rath, Nigam P.

AU - Mirica, Liviu M.

N1 - The tetradentate ligands RN4 (RN4 = N,N′-di-alkyl-2,11-diaza[3,3](2,6)pyridinophane, R = Me or iPr) were found to stabilize cationic (RN4)PdMe2 and (RN4)PdMeCl complexes in both PdIII and PdIV oxidation states. This allows for the first time a direct structural and reactivity comparison of the two Pd oxidati

PY - 2012/1/1

Y1 - 2012/1/1

UR - http://pubs.rsc.org/en/content/articlelanding/2012/dt/c2dt32127k

U2 - 10.1039/c2dt32127k

DO - 10.1039/c2dt32127k

M3 - Article

VL - 41

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Structural and Reactivity Comparison of Analogous Organometallic Pd(III) and Pd(IV) Complexes

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