Stable Bis(Trifluoromethyl)Nickel(III) Complexes

TY - JOUR

T1 - Stable Bis(Trifluoromethyl)Nickel(III) Complexes

AU - Tang, Fengzhi

AU - Rath, Nigam P.

AU - Mirica, Liviu M.

N1 - Organometallic Ni( III) intermediates have been proposed in several Nickel-catalyzed cross-coupling reactions, yet no isolated bis(hydrocarbyl)Ni( III) complexes have been reported to date. Herein we report the synthesis and detailed characterization of stable organometallic Ni( III) complexes that contain two trifluoromethyl ligands and are supported by tetradentate N-donor ligands N4 (R = Me or tBu).

PY - 2015/1/1

Y1 - 2015/1/1

UR - http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C4CC09594D#!divAbstract

U2 - 10.1039/C4CC09594D

DO - 10.1039/C4CC09594D

M3 - Article

VL - 51

JO - Chemical Communications

JF - Chemical Communications

ER -