Sodium-cationized carbohydrate gas-phase fragmentation chemistry: influence of glycosidic linkage position

Jordan M. Rabus; Maha T. Abutokaikah; Reginald T. Ross; Benjamin J. Bythell

doi:10.1039/C7CP04738J

Sodium-cationized carbohydrate gas-phase fragmentation chemistry: influence of glycosidic linkage position

Jordan M. Rabus
, Maha T. Abutokaikah
, Reginald T. Ross
, Benjamin J. Bythell

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Physical Chemistry Chemical Physics
Volume	19
DOIs	https://doi.org/10.1039/C7CP04738J
State	Published - Jan 1 2017

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Organic Chemistry

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@article{db081ebecdca47d0be4d110bd1c1b2c0,

title = "Sodium-cationized carbohydrate gas-phase fragmentation chemistry: influence of glycosidic linkage position",

author = "Rabus, \{Jordan M.\} and Abutokaikah, \{Maha T.\} and Ross, \{Reginald T.\} and Bythell, \{Benjamin J.\}",

note = "We investigate the gas-phase structures and fragmentation chemistry of two isomeric sodium-cationized carbohydrates using combined tandem mass spectrometry, hydrogen/deuterium exchange experiments, and computational methods. Our model systems are the glucose-based disaccharide analytes cellobiose (β- D-glucopyranosyl-(1 → 4)- D-glucose) and gentiobiose (β- D-glucopyranosyl-(1 → 6)- D-glucose). These analytes show substantially different tandem mass spectra.",

year = "2017",

month = jan,

day = "1",

doi = "10.1039/C7CP04738J",

language = "American English",

volume = "19",

journal = "Physical Chemistry Chemical Physics",

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TY - JOUR

T1 - Sodium-cationized carbohydrate gas-phase fragmentation chemistry: influence of glycosidic linkage position

AU - Rabus, Jordan M.

AU - Abutokaikah, Maha T.

AU - Ross, Reginald T.

AU - Bythell, Benjamin J.

N1 - We investigate the gas-phase structures and fragmentation chemistry of two isomeric sodium-cationized carbohydrates using combined tandem mass spectrometry, hydrogen/deuterium exchange experiments, and computational methods. Our model systems are the glucose-based disaccharide analytes cellobiose (β- D-glucopyranosyl-(1 → 4)- D-glucose) and gentiobiose (β- D-glucopyranosyl-(1 → 6)- D-glucose). These analytes show substantially different tandem mass spectra.

PY - 2017/1/1

Y1 - 2017/1/1

UR - http://pubs.rsc.org/en/content/articlelanding/2017/cp/c7cp04738j

U2 - 10.1039/C7CP04738J

DO - 10.1039/C7CP04738J

M3 - Article

VL - 19

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

ER -

Sodium-cationized carbohydrate gas-phase fragmentation chemistry: influence of glycosidic linkage position

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