Reverse Orthogonal Strategy for Oligosaccharide Synthesis

Kohki Fujikawa; N. Vijaya Ganesh; Yih Horng Tan; Keith J. Stine; Alexei V. Demchenko

doi:10.1039/c1cc13409d

Reverse Orthogonal Strategy for Oligosaccharide Synthesis

Kohki Fujikawa, N. Vijaya Ganesh, Yih Horng Tan, Keith J. Stine, Alexei V. Demchenko

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assembly in the reverse direction.

Original language	American English
Journal	Chemical Communications
Volume	47
DOIs	https://doi.org/10.1039/c1cc13409d
State	Published - Jan 1 2011

Disciplines

Organic Chemistry
Biochemistry

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title = "Reverse Orthogonal Strategy for Oligosaccharide Synthesis",

abstract = " Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assembly in the reverse direction. ",

author = "Kohki Fujikawa and Ganesh, \{N. Vijaya\} and Tan, \{Yih Horng\} and Stine, \{Keith J.\} and Demchenko, \{Alexei V.\}",

note = "Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assem Glycochemistry amp; glycobiology",

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doi = "10.1039/c1cc13409d",

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AU - Fujikawa, Kohki

AU - Ganesh, N. Vijaya

AU - Tan, Yih Horng

AU - Stine, Keith J.

AU - Demchenko, Alexei V.

N1 - Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assem Glycochemistry amp; glycobiology

PY - 2011/1/1

Y1 - 2011/1/1

N2 - Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assembly in the reverse direction.

AB - Herein, we report the invention of a novel expeditious concept for oligosaccharide synthesis. Unlike the classic orthogonal strategy based on leaving groups, the reverse approach is based on orthogonal protecting groups, herein p-methoxybenzyl and 4-pentenoyl, which allows for efficient oligosaccharide assembly in the reverse direction.

UR - https://pubs.rsc.org/en/content/articlelanding/2011/cc/c1cc13409d

UR - http://pubs.rsc.org/en/content/articlelanding/2011/cc/c1cc13409d

U2 - 10.1039/c1cc13409d

DO - 10.1039/c1cc13409d

M3 - Article

VL - 47

JO - Chemical Communications

JF - Chemical Communications

ER -

Reverse Orthogonal Strategy for Oligosaccharide Synthesis

Abstract

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