“Reverse” engineering: Toward 0-D cadmium halide clusters

Christina E. Costin-Hogan; Chun-Long Chen; Emma Hughes; Austin Pickett; Richard Valencia; Nigam Rath; Alicia M. Beatty

doi:10.1039/B812504J

“Reverse” engineering: Toward 0-D cadmium halide clusters

Christina E. Costin-Hogan, Chun-Long Chen, Emma Hughes, Austin Pickett, Richard Valencia, Nigam Rath, Alicia M. Beatty

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

Crystal structures having distinct structural motifs (0-D, 1-D, 2-D), are reported—the results of reactions of ortho -substituted phenylamines with cadmium halide salts. The aim of the study was to control the size and dimensionality of Cd(II) halide assemblies by changing the steric demands of the ortho substituents. The ultimate goal of the research is to synthesize cadmium halide clusters using rational and predictable methods. To this end, the synthesis and crystal structure of a new Cd 3 Cl 126− cluster are also reported.

Original language	American English
Journal	CrystEngComm
Volume	10
DOIs	https://doi.org/10.1039/B812504J
State	Published - Oct 17 2008

Disciplines

Biochemical and Biomolecular Engineering
Life Sciences
Biochemistry, Biophysics, and Structural Biology
Biochemistry
Organic Chemistry
Inorganic Chemistry

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abstract = " Crystal structures having distinct structural motifs (0-D, 1-D, 2-D), are reported—the results of reactions of ortho -substituted phenylamines with cadmium halide salts. The aim of the study was to control the size and dimensionality of Cd(II) halide assemblies by changing the steric demands of the ortho substituents. The ultimate goal of the research is to synthesize cadmium halide clusters using rational and predictable methods. To this end, the synthesis and crystal structure of a new Cd 3 Cl 126− cluster are also reported. ",

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AU - Costin-Hogan, Christina E.

AU - Chen, Chun-Long

AU - Hughes, Emma

AU - Pickett, Austin

AU - Valencia, Richard

AU - Rath, Nigam

AU - Beatty, Alicia M.

N1 - Crystal structures having distinct structural motifs (0-D, 1-D, 2-D), are reported-the results of reactions of ortho-substituted phenylamines with cadmium halide salts. The aim of the study was to control the size and dimensionality of Cd(II) halide assemblies by changing the steric demands of the ortho subs

PY - 2008/10/17

Y1 - 2008/10/17

N2 - Crystal structures having distinct structural motifs (0-D, 1-D, 2-D), are reported—the results of reactions of ortho -substituted phenylamines with cadmium halide salts. The aim of the study was to control the size and dimensionality of Cd(II) halide assemblies by changing the steric demands of the ortho substituents. The ultimate goal of the research is to synthesize cadmium halide clusters using rational and predictable methods. To this end, the synthesis and crystal structure of a new Cd 3 Cl 126− cluster are also reported.

AB - Crystal structures having distinct structural motifs (0-D, 1-D, 2-D), are reported—the results of reactions of ortho -substituted phenylamines with cadmium halide salts. The aim of the study was to control the size and dimensionality of Cd(II) halide assemblies by changing the steric demands of the ortho substituents. The ultimate goal of the research is to synthesize cadmium halide clusters using rational and predictable methods. To this end, the synthesis and crystal structure of a new Cd 3 Cl 126− cluster are also reported.

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M3 - Article

VL - 10

JO - CrystEngComm

JF - CrystEngComm

ER -

“Reverse” engineering: Toward 0-D cadmium halide clusters

Abstract

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