Probing the importance of electrostatic interactions of Ce(III) with the phosphodiester backbone during transesterification using methyl phosphonates

Todd A. Osiek; James K. Bashkin

doi:10.1039/B003130P

Probing the importance of electrostatic interactions of Ce(III) with the phosphodiester backbone during transesterification using methyl phosphonates

Todd A. Osiek
, James K. Bashkin

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	New Journal of Chemistry
Volume	25
DOIs	https://doi.org/10.1039/B003130P
State	Published - Jan 1 2001
Externally published	Yes

Disciplines

Organic Chemistry
Inorganic Chemistry

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10.1039/B003130PLicense: Unspecified

Cite this

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title = "Probing the importance of electrostatic interactions of Ce(III) with the phosphodiester backbone during transesterification using methyl phosphonates",

author = "Osiek, \{Todd A.\} and Bashkin, \{James K.\}",

note = "This paper investigates aspects of the fundamental mechanism of transesterification and hydrolysis. The ability of remote phosphates to coordinate and deliver metal catalysts to the active site (the 2′-OH) of an RNA residue is reported. Previous literature reports show that ApUp is cleaved much faster than ApU at",

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doi = "10.1039/B003130P",

language = "American English",

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AU - Osiek, Todd A.

AU - Bashkin, James K.

N1 - This paper investigates aspects of the fundamental mechanism of transesterification and hydrolysis. The ability of remote phosphates to coordinate and deliver metal catalysts to the active site (the 2′-OH) of an RNA residue is reported. Previous literature reports show that ApUp is cleaved much faster than ApU at

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U2 - 10.1039/B003130P

DO - 10.1039/B003130P

M3 - Article

VL - 25

JO - New Journal of Chemistry

JF - New Journal of Chemistry

ER -

Probing the importance of electrostatic interactions of Ce(III) with the phosphodiester backbone during transesterification using methyl phosphonates

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