Paradigms and paradoxes: properties of ideal gases for large and small species

James S. Chickos; Joel F. Liebman

doi:10.1007/s11224-009-9511-3

Paradigms and paradoxes: properties of ideal gases for large and small species

James S. Chickos, Joel F. Liebman

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

We ask the question, ‘‘In the absence of intermolecular interactions, when are ideal gases not ideal?’’ We find two cherished equations become problematic when the size of the molecule becomes too big or its mass is too small.

Original language	American English
Journal	Structural Chemistry
Volume	20
DOIs	https://doi.org/10.1007/s11224-009-9511-3
State	Published - Jan 12 2009

Keywords

Absolute entropy
Available space
Cherished equations
Intermolecular forces
Positronium
Translational entropy

Disciplines

Analytical Chemistry

Access to Document

10.1007/s11224-009-9511-3License: Unspecified

Cite this

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abstract = " We ask the question, {\textquoteleft}{\textquoteleft}In the absence of intermolecular interactions, when are ideal gases not ideal?{\textquoteright}{\textquoteright} We find two cherished equations become problematic when the size of the molecule becomes too big or its mass is too small.",

keywords = "Absolute entropy, Available space, Cherished equations, Intermolecular forces, Positronium, Translational entropy",

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AU - Liebman, Joel F.

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KW - Absolute entropy

KW - Available space

KW - Cherished equations

KW - Intermolecular forces

KW - Positronium

KW - Translational entropy

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M3 - Article

VL - 20

JO - Structural Chemistry

JF - Structural Chemistry

ER -

Paradigms and paradoxes: properties of ideal gases for large and small species

Abstract

Keywords

Disciplines

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