N,N',N''-Tris(p-methoxy­phenyl)­phospho­ric triamide

Nigam Rath

doi:10.1107/S0108270105031720

N,N',N''-Tris(p-methoxyphenyl)phosphoric triamide

Nigam Rath

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

<div class="line" id="line-11"> The title compound, C 21 H 24 N 3 O 4 P, is a self-complementary hydrogen-bond (HB) building unit, with (P=)O as the primary HB acceptor and N-H as the HB donor. Each of the four crystallographically distinct and nearly parallel molecules of the unit cell has a net dipole moment along the P=O bond direction and all of the dipoles are directed in the same general crystallographic direction. Head-to-tail N-H <img src="http://scripts.iucr.org/logos/entities/ctdot_rmgif.gif"/> O=P double-HB strands stack adjacent molecules into one-dimensional infinite polar columns. Each polar column is a 2 1  helix and all columns are essentially parallel, resulting in polar order throughout the entire crystal. </div>

Original language	American English
Journal	Acta Crystallographica
Volume	61
DOIs	https://doi.org/10.1107/S0108270105031720
State	Published - 2005

Disciplines

Life Sciences
Biochemistry, Biophysics, and Structural Biology
Biochemistry

Access to Document

10.1107/S0108270105031720License: Unspecified

Cite this

@article{ceabc917d8c34d258493c52f8f9acbb8,

title = "N,N',N''-Tris(p-methoxyphenyl)phosphoric triamide",

abstract = " The title compound, C 21 H 24 N 3 O 4 P, is a self-complementary hydrogen-bond (HB) building unit, with (P=)O as the primary HB acceptor and N-H as the HB donor. Each of the four crystallographically distinct and nearly parallel molecules of the unit cell has a net dipole moment along the P=O bond direction and all of the dipoles are directed in the same general crystallographic direction. Head-to-tail N-H O=P double-HB strands stack adjacent molecules into one-dimensional infinite polar columns. Each polar column is a 2 1  helix and all columns are essentially parallel, resulting in polar order throughout the entire crystal. ",

author = "Nigam Rath",

note = "The title compound, CHNOP, is a self-complementary hydrogen-bond (HB) building unit, with (P=)O as the primary HB acceptor and N-H as the HB donor. Each of the four crystallographically distinct and nearly parallel molecules of the unit cell has a net dipole moment along the P=O bond direction and all of the dipoles are directed in the same general crystallographic direction.",

year = "2005",

doi = "10.1107/S0108270105031720",

language = "American English",

volume = "61",

journal = "Acta Crystallographica",

}

TY - JOUR

T1 - N,N',N''-Tris(p-methoxyphenyl)phosphoric triamide

AU - Rath, Nigam

N1 - The title compound, CHNOP, is a self-complementary hydrogen-bond (HB) building unit, with (P=)O as the primary HB acceptor and N-H as the HB donor. Each of the four crystallographically distinct and nearly parallel molecules of the unit cell has a net dipole moment along the P=O bond direction and all of the dipoles are directed in the same general crystallographic direction.

PY - 2005

Y1 - 2005

N2 - The title compound, C 21 H 24 N 3 O 4 P, is a self-complementary hydrogen-bond (HB) building unit, with (P=)O as the primary HB acceptor and N-H as the HB donor. Each of the four crystallographically distinct and nearly parallel molecules of the unit cell has a net dipole moment along the P=O bond direction and all of the dipoles are directed in the same general crystallographic direction. Head-to-tail N-H O=P double-HB strands stack adjacent molecules into one-dimensional infinite polar columns. Each polar column is a 2 1  helix and all columns are essentially parallel, resulting in polar order throughout the entire crystal.

AB - The title compound, C 21 H 24 N 3 O 4 P, is a self-complementary hydrogen-bond (HB) building unit, with (P=)O as the primary HB acceptor and N-H as the HB donor. Each of the four crystallographically distinct and nearly parallel molecules of the unit cell has a net dipole moment along the P=O bond direction and all of the dipoles are directed in the same general crystallographic direction. Head-to-tail N-H O=P double-HB strands stack adjacent molecules into one-dimensional infinite polar columns. Each polar column is a 2 1  helix and all columns are essentially parallel, resulting in polar order throughout the entire crystal.

UR - https://doi.org/10.1107/S0108270105031720

U2 - 10.1107/S0108270105031720

DO - 10.1107/S0108270105031720

M3 - Article

VL - 61

JO - Acta Crystallographica

JF - Acta Crystallographica

ER -