Morphologies of branched-chain pyrogallol[4]arenes in the solid state

Oleg V. Kulikov; Saeedeh Negin; Nigam Rath; George W. Gokel

doi:10.1080/10610278.2013.860228

Morphologies of branched-chain pyrogallol[4]arenes in the solid state

Oleg V. Kulikov, Saeedeh Negin, Nigam Rath, George W. Gokel

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

A suite of branched-chain pyrogallol[4]arene (Pg) macrocycles, most of which show activity in bilayer membranes, has been prepared and studied by X-ray crystallography. The little-known branched side-chain Pgs include 2-propyl, 2-butyl, 2-pentyl, 3-pentyl, 3-heptyl, 4-heptyl, 5-nonyl and cyclohexyl. The Pgs form self-assembled structures having bilayer, capsule or, in one case, a nanotube morphology. The nanotube structure observed for C -(di- n -ethyl)pyrogallol[4]arene was confirmed by X-ray structure analysis and by transmission and scanning electron microscopies.

Original language	American English
Journal	Supramolecular Chemistry
Volume	26
DOIs	https://doi.org/10.1080/10610278.2013.860228
State	Published - Feb 5 2014

Keywords

X-ray structure
bilayer
nanocapsule
nanotube
pyrogallolarene

Disciplines

Life Sciences
Biochemistry, Biophysics, and Structural Biology
Biochemistry

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10.1080/10610278.2013.860228License: Unspecified

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title = "Morphologies of branched-chain pyrogallol[4]arenes in the solid state",

abstract = " A suite of branched-chain pyrogallol[4]arene (Pg) macrocycles, most of which show activity in bilayer membranes, has been prepared and studied by X-ray crystallography. The little-known branched side-chain Pgs include 2-propyl, 2-butyl, 2-pentyl, 3-pentyl, 3-heptyl, 4-heptyl, 5-nonyl and cyclohexyl. The Pgs form self-assembled structures having bilayer, capsule or, in one case, a nanotube morphology. The nanotube structure observed for C -(di- n -ethyl)pyrogallol[4]arene was confirmed by X-ray structure analysis and by transmission and scanning electron microscopies. ",

keywords = "X-ray structure, bilayer, nanocapsule, nanotube, pyrogallolarene",

author = "Kulikov, {Oleg V.} and Saeedeh Negin and Nigam Rath and Gokel, {George W.}",

note = "A suite of branched-chain pyrogallol[4]arene (Pg) macrocycles, most of which show activity in bilayer membranes, has been prepared and studied by X-ray crystallography. The little-known branched side-chain Pgs include 2-propyl, 2-butyl, 2-pentyl, 3-pentyl, 3-heptyl, 4-heptyl, 5-nonyl and cyclohexyl. The Pgs form self-assembled structures having bilayer, capsule or, in one case, a nanotube morphology.",

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doi = "10.1080/10610278.2013.860228",

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T1 - Morphologies of branched-chain pyrogallol[4]arenes in the solid state

AU - Kulikov, Oleg V.

AU - Negin, Saeedeh

AU - Rath, Nigam

AU - Gokel, George W.

N1 - A suite of branched-chain pyrogallol[4]arene (Pg) macrocycles, most of which show activity in bilayer membranes, has been prepared and studied by X-ray crystallography. The little-known branched side-chain Pgs include 2-propyl, 2-butyl, 2-pentyl, 3-pentyl, 3-heptyl, 4-heptyl, 5-nonyl and cyclohexyl. The Pgs form self-assembled structures having bilayer, capsule or, in one case, a nanotube morphology.

PY - 2014/2/5

Y1 - 2014/2/5

N2 - A suite of branched-chain pyrogallol[4]arene (Pg) macrocycles, most of which show activity in bilayer membranes, has been prepared and studied by X-ray crystallography. The little-known branched side-chain Pgs include 2-propyl, 2-butyl, 2-pentyl, 3-pentyl, 3-heptyl, 4-heptyl, 5-nonyl and cyclohexyl. The Pgs form self-assembled structures having bilayer, capsule or, in one case, a nanotube morphology. The nanotube structure observed for C -(di- n -ethyl)pyrogallol[4]arene was confirmed by X-ray structure analysis and by transmission and scanning electron microscopies.

AB - A suite of branched-chain pyrogallol[4]arene (Pg) macrocycles, most of which show activity in bilayer membranes, has been prepared and studied by X-ray crystallography. The little-known branched side-chain Pgs include 2-propyl, 2-butyl, 2-pentyl, 3-pentyl, 3-heptyl, 4-heptyl, 5-nonyl and cyclohexyl. The Pgs form self-assembled structures having bilayer, capsule or, in one case, a nanotube morphology. The nanotube structure observed for C -(di- n -ethyl)pyrogallol[4]arene was confirmed by X-ray structure analysis and by transmission and scanning electron microscopies.

KW - X-ray structure

KW - bilayer

KW - nanocapsule

KW - nanotube

KW - pyrogallolarene

UR - https://doi.org/10.1080/10610278.2013.860228

U2 - 10.1080/10610278.2013.860228

DO - 10.1080/10610278.2013.860228

M3 - Article

VL - 26

JO - Supramolecular Chemistry

JF - Supramolecular Chemistry

ER -

Morphologies of branched-chain pyrogallol[4]arenes in the solid state

Abstract

Keywords

Disciplines

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