Matching of host and guest symmetry in crystalline lattice inclusion complexes of the triaroylbenzene derivative 1,3,5-tris(3-methoxybenzoyl)benzene

V.S. Senthil Kumar; F. Christopher Pigge; Nigam Rath

doi:10.1039/B413264E

Matching of host and guest symmetry in crystalline lattice inclusion complexes of the triaroylbenzene derivative 1,3,5-tris(3-methoxybenzoyl)benzene

V.S. Senthil Kumar, F. Christopher Pigge, Nigam Rath

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

<div class="line" id="line-11"> Conformationally flexible 1,3,5-tris(3-methoxybenzoyl)benzene was found to form isomorphous lattice-type inclusion adducts with benzene, acetone and trimethylamine  N -oxide (TMNO). All three inclusion complexes crystallize in the three-fold symmetric space group  P <img src="https://www.rsc.org/images/entities/char_0033_0304.gif"/>  which correlates with the  C 3  molecular symmetry evident in the triaroylbenzene hosts and enclathrated guests. Inclusion complexes were not obtained when the title compound was crystallized from larger solvents or solvents lacking trigonal symmetry elements. Thus, it appears that reinforcing symmetry properties of host and guest act in tandem to afford highly symmetrical (trigonal/hexagonal) clathrates. </div>

Original language	American English
Journal	CrystEngComm
Volume	6
DOIs	https://doi.org/10.1039/B413264E
State	Published - 2004

Disciplines

Life Sciences
Biochemistry, Biophysics, and Structural Biology

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title = "Matching of host and guest symmetry in crystalline lattice inclusion complexes of the triaroylbenzene derivative 1,3,5-tris(3-methoxybenzoyl)benzene",

abstract = " Conformationally flexible 1,3,5-tris(3-methoxybenzoyl)benzene was found to form isomorphous lattice-type inclusion adducts with benzene, acetone and trimethylamine  N -oxide (TMNO). All three inclusion complexes crystallize in the three-fold symmetric space group  P  which correlates with the  C 3  molecular symmetry evident in the triaroylbenzene hosts and enclathrated guests. Inclusion complexes were not obtained when the title compound was crystallized from larger solvents or solvents lacking trigonal symmetry elements. Thus, it appears that reinforcing symmetry properties of host and guest act in tandem to afford highly symmetrical (trigonal/hexagonal) clathrates. ",

author = "Kumar, {V.S. Senthil} and Pigge, {F. Christopher} and Nigam Rath",

note = "Conformationally flexible 1,3,5-tris(3-methoxybenzoyl)benzene was found to form isomorphous lattice-type inclusion adducts with benzene, acetone and trimethylamine N-oxide (TMNO). All three inclusion complexes crystallize in the three-fold symmetric space group P which correlates with the C 3 molecular symmetry evident in the triaroylbenzene hosts and enclathrated guests.",

year = "2004",

doi = "10.1039/B413264E",

language = "American English",

volume = "6",

journal = "CrystEngComm",

}

TY - JOUR

T1 - Matching of host and guest symmetry in crystalline lattice inclusion complexes of the triaroylbenzene derivative 1,3,5-tris(3-methoxybenzoyl)benzene

AU - Kumar, V.S. Senthil

AU - Pigge, F. Christopher

AU - Rath, Nigam

N1 - Conformationally flexible 1,3,5-tris(3-methoxybenzoyl)benzene was found to form isomorphous lattice-type inclusion adducts with benzene, acetone and trimethylamine N-oxide (TMNO). All three inclusion complexes crystallize in the three-fold symmetric space group P which correlates with the C 3 molecular symmetry evident in the triaroylbenzene hosts and enclathrated guests.

PY - 2004

Y1 - 2004

N2 - Conformationally flexible 1,3,5-tris(3-methoxybenzoyl)benzene was found to form isomorphous lattice-type inclusion adducts with benzene, acetone and trimethylamine  N -oxide (TMNO). All three inclusion complexes crystallize in the three-fold symmetric space group  P  which correlates with the  C 3  molecular symmetry evident in the triaroylbenzene hosts and enclathrated guests. Inclusion complexes were not obtained when the title compound was crystallized from larger solvents or solvents lacking trigonal symmetry elements. Thus, it appears that reinforcing symmetry properties of host and guest act in tandem to afford highly symmetrical (trigonal/hexagonal) clathrates.

AB - Conformationally flexible 1,3,5-tris(3-methoxybenzoyl)benzene was found to form isomorphous lattice-type inclusion adducts with benzene, acetone and trimethylamine  N -oxide (TMNO). All three inclusion complexes crystallize in the three-fold symmetric space group  P  which correlates with the  C 3  molecular symmetry evident in the triaroylbenzene hosts and enclathrated guests. Inclusion complexes were not obtained when the title compound was crystallized from larger solvents or solvents lacking trigonal symmetry elements. Thus, it appears that reinforcing symmetry properties of host and guest act in tandem to afford highly symmetrical (trigonal/hexagonal) clathrates.

UR - https://doi.org/10.1039/B413264E

U2 - 10.1039/B413264E

DO - 10.1039/B413264E

M3 - Article

VL - 6

JO - CrystEngComm

JF - CrystEngComm

ER -

Matching of host and guest symmetry in crystalline lattice inclusion complexes of the triaroylbenzene derivative 1,3,5-tris(3-methoxybenzoyl)benzene

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