Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

Xuyang He; Bruce C. Noll; Alicia Beatty; Robert E. Mulvey; Kenneth W. Henderson

doi:10.1021/ja048750m

Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

Xuyang He
, Bruce C. Noll
, Alicia Beatty
, Robert E. Mulvey
, Kenneth W. Henderson

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of the American Chemical Society
Volume	126
DOIs	https://doi.org/10.1021/ja048750m
State	Published - Jan 6 2004
Externally published	Yes

Disciplines

Organic Chemistry
Inorganic Chemistry

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10.1021/ja048750mLicense: Unspecified

Cite this

Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates. / He, Xuyang; Noll, Bruce C.; Beatty, Alicia et al.
In: Journal of the American Chemical Society, Vol. 126, 06.01.2004.

Research output: Contribution to journal › Article › peer-review

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title = "Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates",

author = "Xuyang He and Noll, \{Bruce C.\} and Alicia Beatty and Mulvey, \{Robert E.\} and Henderson, \{Kenneth W.\}",

note = "Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.",

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AU - Noll, Bruce C.

AU - Beatty, Alicia

AU - Mulvey, Robert E.

AU - Henderson, Kenneth W.

N1 - Potassium, calcium, and mixed potassium-calcium amide combinations have been shown to be efficient reagents in enolization reactions, and a set of representative intermediate mono- and heterobimetallic enolates have been successfully isolated and crystallographically characterized.

PY - 2004/1/6

Y1 - 2004/1/6

UR - https://pure.strath.ac.uk/portal/en/publications/ketone-deprotonation-mediated-by-mono-and-heterobimetallic-alkali-and-alkaline-earth-metal-amide-bases-structural-characterization-of-potassium-calcium-and-mixed-potassiumcalcium-enolates(e67ff023-e8d7-40c2-9b06-e1b82724eaae).html

U2 - 10.1021/ja048750m

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M3 - Article

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

ER -

Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: Structural characterization of potassium, calcium, and mixed potassium-calcium enolates

Disciplines

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