@article{09c2d28a63814f429b1a4487cc11ecb9,
title = "Isomerization in bent phosphametallocenes : Combining rotational barriers and the intramolecular slip-inversion-slip mechanism to control stereo-conformation",
author = "Freeman, {William P.} and Ahn, {Yi Joon} and Hollis, {T. Keith} and Whitaker, {J. Andrew} and Vargas, {Victor C.} and Rubio, {Ramel J.} and Alingog, {Karen D.} and Bauer, {Eike B.} and Tham, {Fook S.}",
note = "Four new phosphazirconocenes, [(4,5,6-trihydro-1-phosphapentalenyl) 2ZrCl 2] ( 8), [(4,5,6,7-tetrahydro-1-phosphindolyl) 2ZrCl 2] ( 9), [(4,5,6,7,8-pentahydro-1-phosphazulenyl) 2ZrCl 2] ( 10), (2,4-dimethylphospholyl) 2ZrCl 2 ( 11), were prepared and characterized. A crystal structure of [(4,5,6,7-tetrahydro-1-phosphindolyl) 2ZrCl 2] ( 9), was obtained that revealed disorder ( rac and meso isomers in the same crystal) and demonstrates unambiguously the meso configuration in the bent early transition metal phosphametallocenes.",
year = "2008",
month = jul,
day = "1",
doi = "10.1016/j.jorganchem.2008.04.021",
language = "American English",
volume = "693",
journal = "Journal of Organometallic Chemistry",
}