Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion

Patrina Paraskevopoulou; Christodoulos Makedonas; Nikolaos Psaroudakis; Christiana A. Mitsopoulou; Georgios Floros; Andriana Seressioti; Marinos Loannou; Yiannis Sanakis; Nigam Rath; Carlos J. Gomez Garcia; Pericles Stavropoulos; Konstantinos Mertis

doi:10.1021/ic901432j

Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion

Patrina Paraskevopoulou
, Christodoulos Makedonas
, Nikolaos Psaroudakis
, Christiana A. Mitsopoulou
, Georgios Floros
, Andriana Seressioti
, Marinos Loannou
, Yiannis Sanakis
, Nigam Rath
, Carlos J. Gomez Garcia
, Pericles Stavropoulos
, Konstantinos Mertis

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Inorganic Chemistry
Volume	49
DOIs	https://doi.org/10.1021/ic901432j
State	Published - Mar 1 2010

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Chemistry
Inorganic Chemistry

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@article{ed7e2359291e4b89bf9344b453c296dd,

title = "Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion",

author = "Patrina Paraskevopoulou and Christodoulos Makedonas and Nikolaos Psaroudakis and Mitsopoulou, \{Christiana A.\} and Georgios Floros and Andriana Seressioti and Marinos Loannou and Yiannis Sanakis and Nigam Rath and Garcia, \{Carlos J. Gomez\} and Pericles Stavropoulos and Konstantinos Mertis",

note = "The novel trimolybdenum cluster [Mo3(μ 3-Br)2(μ -Br)3Br6]2- (1, \{Mo3\}9+, 9 d-electrons) has been isolated from the reaction of [Mo(CO)6] with 1,2-C2H4Br2 in refluxing PhCl. The compound has been characterized in solution by electrospray ionization mass spectrometry (ESI-MS), UV-vis spectroscopy, cyclic voltammetry, and in the solid state by X-ray analysis (counter-cations: (n-Bu)4N+ (1), Et4N+, Et3BzN+), electron paramagnetic resonance (EPR), magnetic susceptibility measurements, and infrared spectroscopy.",

year = "2010",

month = mar,

day = "1",

doi = "10.1021/ic901432j",

language = "American English",

volume = "49",

journal = "Inorganic Chemistry",

}

TY - JOUR

T1 - Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion

AU - Paraskevopoulou, Patrina

AU - Makedonas, Christodoulos

AU - Psaroudakis, Nikolaos

AU - Mitsopoulou, Christiana A.

AU - Floros, Georgios

AU - Seressioti, Andriana

AU - Loannou, Marinos

AU - Sanakis, Yiannis

AU - Rath, Nigam

AU - Garcia, Carlos J. Gomez

AU - Stavropoulos, Pericles

AU - Mertis, Konstantinos

N1 - The novel trimolybdenum cluster [Mo3(μ 3-Br)2(μ -Br)3Br6]2- (1, {Mo3}9+, 9 d-electrons) has been isolated from the reaction of [Mo(CO)6] with 1,2-C2H4Br2 in refluxing PhCl. The compound has been characterized in solution by electrospray ionization mass spectrometry (ESI-MS), UV-vis spectroscopy, cyclic voltammetry, and in the solid state by X-ray analysis (counter-cations: (n-Bu)4N+ (1), Et4N+, Et3BzN+), electron paramagnetic resonance (EPR), magnetic susceptibility measurements, and infrared spectroscopy.

PY - 2010/3/1

Y1 - 2010/3/1

UR - http://scholarsmine.mst.edu/chem_facwork/325/

U2 - 10.1021/ic901432j

DO - 10.1021/ic901432j

M3 - Article

VL - 49

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion

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