Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion

Patrina Paraskevopoulou; Christodoulos Makedonas; Nikolaos Psaroudakis; Christiana A. Mitsopoulou; Georgios Floros; Andriana Seressioti; Marinos Loannou; Yiannis Sanakis; Nigam Rath; Carlos J. Gomez Garcia; Pericles Stavropoulos; Konstantinos Mertis

doi:10.1021/ic901432j

Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion

Patrina Paraskevopoulou, Christodoulos Makedonas, Nikolaos Psaroudakis, Christiana A. Mitsopoulou, Georgios Floros, Andriana Seressioti, Marinos Loannou, Yiannis Sanakis, Nigam Rath, Carlos J. Gomez Garcia, Pericles Stavropoulos, Konstantinos Mertis

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Inorganic Chemistry
Volume	49
DOIs	https://doi.org/10.1021/ic901432j
State	Published - Mar 1 2010

Disciplines

Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic901432jLicense: Unspecified

Cite this

@article{ed7e2359291e4b89bf9344b453c296dd,

title = "Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion",

author = "Patrina Paraskevopoulou and Christodoulos Makedonas and Nikolaos Psaroudakis and Mitsopoulou, {Christiana A.} and Georgios Floros and Andriana Seressioti and Marinos Loannou and Yiannis Sanakis and Nigam Rath and Garcia, {Carlos J. Gomez} and Pericles Stavropoulos and Konstantinos Mertis",

note = "The novel trimolybdenum cluster [Mo3(μ 3-Br)2(μ -Br)3Br6]2- (1, {Mo3}9+, 9 d-electrons) has been isolated from the reaction of [Mo(CO)6] with 1,2-C2H4Br2 in refluxing PhCl. The compound has been characterized in solution by electrospray ionization mass spectrometry (ESI-MS), UV-vis spectroscopy, cyclic voltammetry, and in the solid state by X-ray analysis (counter-cations: (n-Bu)4N+ (1), Et4N+, Et3BzN+), electron paramagnetic resonance (EPR), magnetic susceptibility measurements, and infrared spectroscopy.",

year = "2010",

month = mar,

day = "1",

doi = "10.1021/ic901432j",

language = "American English",

volume = "49",

journal = "Inorganic Chemistry",

}

TY - JOUR

T1 - Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion

AU - Paraskevopoulou, Patrina

AU - Makedonas, Christodoulos

AU - Psaroudakis, Nikolaos

AU - Mitsopoulou, Christiana A.

AU - Floros, Georgios

AU - Seressioti, Andriana

AU - Loannou, Marinos

AU - Sanakis, Yiannis

AU - Rath, Nigam

AU - Garcia, Carlos J. Gomez

AU - Stavropoulos, Pericles

AU - Mertis, Konstantinos

N1 - The novel trimolybdenum cluster [Mo3(μ 3-Br)2(μ -Br)3Br6]2- (1, {Mo3}9+, 9 d-electrons) has been isolated from the reaction of [Mo(CO)6] with 1,2-C2H4Br2 in refluxing PhCl. The compound has been characterized in solution by electrospray ionization mass spectrometry (ESI-MS), UV-vis spectroscopy, cyclic voltammetry, and in the solid state by X-ray analysis (counter-cations: (n-Bu)4N+ (1), Et4N+, Et3BzN+), electron paramagnetic resonance (EPR), magnetic susceptibility measurements, and infrared spectroscopy.

PY - 2010/3/1

Y1 - 2010/3/1

UR - http://scholarsmine.mst.edu/chem_facwork/325/

U2 - 10.1021/ic901432j

DO - 10.1021/ic901432j

M3 - Article

VL - 49

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

Isolation, Characterization, and Computational Studies of the Novel [Mo3(μ3-Br)2(μ-Br)3Br6]2― Cluster Anion

Disciplines

Access to Document

Other files and links

Cite this