Intramolecular Glycosylation

Alexei Demchenko; Xiao G. Jia

doi:10.3762/bjoc.13.201

Intramolecular Glycosylation

Alexei Demchenko, Xiao G. Jia

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

Carbohydrate oligomers remain challenging targets for chemists due to the requirement for elaborate protecting and leaving group manipulations, functionalization, tedious purification, and sophisticated characterization. Achieving high stereocontrol in glycosylation reactions is arguably the major hurdle that chemists experience. This review article overviews methods for intramolecular glycosylation reactions wherein the facial stereoselectivity is achieved by tethering of the glycosyl donor and acceptor counterparts.

Original language	American English
Journal	Beilstein Journal of Organic Chemistry
Volume	13
DOIs	https://doi.org/10.3762/bjoc.13.201
State	Published - Sep 29 2017

Disciplines

Chemistry

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Cite this

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title = "Intramolecular Glycosylation",

abstract = " Carbohydrate oligomers remain challenging targets for chemists due to the requirement for elaborate protecting and leaving group manipulations, functionalization, tedious purification, and sophisticated characterization. Achieving high stereocontrol in glycosylation reactions is arguably the major hurdle that chemists experience. This review article overviews methods for intramolecular glycosylation reactions wherein the facial stereoselectivity is achieved by tethering of the glycosyl donor and acceptor counterparts.",

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