Fragmentation Pathways of Lithiated Hexose Monosaccharides

TY - JOUR

T1 - Fragmentation Pathways of Lithiated Hexose Monosaccharides

AU - Abutokaikah, Maha T.

AU - Frye, Joseph W.

AU - Tschampel, John

AU - Rabus, Jordan M.

AU - Bythell, Benjamin J.

N1 - Maha T. Abutokaikah Joseph W. Frye John Tschampel Jordan M. Rabus Benjamin J. Bythell We characterize the primary fragmentation reactions of three isomeric lithiated D-hexose sugars (glucose, galactose, and mannose) utilizing tandem mass spectrometry, regiospecific labeling, and theory. We provide evidence that these three isomers populate similar fragmentation pathways to produce the abundant cross-ring cleavage peaks ( 0,2A 1 and 0,3A 1).

PY - 2018/8/1

Y1 - 2018/8/1

UR - https://link.springer.com/content/pdf/10.1007%2Fs13361-018-1973-3.pdf

U2 - 10.1007/s13361-018-1973-3

DO - 10.1007/s13361-018-1973-3

M3 - Article

VL - 29

JO - Journal of the American Society for Mass Spectrometry

JF - Journal of the American Society for Mass Spectrometry

ER -