Effect of the Sixth Axial Ligand in CS-Ligated Iron(II)octaethylporphyrinates: Structural and Mössbauer Studies

Changsheng Cao; S. Dahal; Mayou Shang; Alicia M. Beatty; Wendy Hibbs; Charles E. Schulz; W. Robert Scheidt

doi:10.1021/ic030043r

Effect of the Sixth Axial Ligand in CS-Ligated Iron(II)octaethylporphyrinates: Structural and Mössbauer Studies

Changsheng Cao
, S. Dahal
, Mayou Shang
, Alicia M. Beatty
, Wendy Hibbs
, Charles E. Schulz
, W. Robert Scheidt

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Inorganic Chemistry
Volume	42
DOIs	https://doi.org/10.1021/ic030043r
State	Published - Jan 8 2003
Externally published	Yes

Disciplines

Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic030043rLicense: Unspecified

Cite this

@article{aaa9441bb51449b7a92c7a95857c90fc,

title = "Effect of the Sixth Axial Ligand in CS-Ligated Iron(II)octaethylporphyrinates: Structural and M{\"o}ssbauer Studies",

author = "Changsheng Cao and S. Dahal and Mayou Shang and Beatty, \{Alicia M.\} and Wendy Hibbs and Schulz, \{Charles E.\} and Scheidt, \{W. Robert\}",

note = "The effect of a sixth ligand in a series of low-spin thiocarbonyl-ligated iron(II)octaethylporphyrinates has been investigated. Six-coordinate complexes have been synthesized and characterized by M{\"o}ssbauer and infrared spectroscopy and single-crystal X-ray structure determinations. The results are compared with the five-coordinate parent complex. The crystal structures of [Fe(OEP)(CS)(1-MeIm)] and [Fe(OEP)(CS)(Py)] are reported and discussed.",

year = "2003",

month = jan,

day = "8",

doi = "10.1021/ic030043r",

language = "American English",

volume = "42",

journal = "Inorganic Chemistry",

}

TY - JOUR

T1 - Effect of the Sixth Axial Ligand in CS-Ligated Iron(II)octaethylporphyrinates: Structural and Mössbauer Studies

AU - Cao, Changsheng

AU - Dahal, S.

AU - Shang, Mayou

AU - Beatty, Alicia M.

AU - Hibbs, Wendy

AU - Schulz, Charles E.

AU - Scheidt, W. Robert

N1 - The effect of a sixth ligand in a series of low-spin thiocarbonyl-ligated iron(II)octaethylporphyrinates has been investigated. Six-coordinate complexes have been synthesized and characterized by Mössbauer and infrared spectroscopy and single-crystal X-ray structure determinations. The results are compared with the five-coordinate parent complex. The crystal structures of [Fe(OEP)(CS)(1-MeIm)] and [Fe(OEP)(CS)(Py)] are reported and discussed.

PY - 2003/1/8

Y1 - 2003/1/8

UR - https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1993896/

U2 - 10.1021/ic030043r

DO - 10.1021/ic030043r

M3 - Article

VL - 42

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

Effect of the Sixth Axial Ligand in CS-Ligated Iron(II)octaethylporphyrinates: Structural and Mössbauer Studies

Disciplines

Access to Document

Other files and links

Cite this