Dioxygen Activation by an Organometallic Pd(Ii) Precursor: Formation of a Pd(IV)–OH Complex and Its C–O Bond Formation Reactivity

Fengrui Qu; Julia R. Khusnutdinova; Nigam P. Rath; Liviu M. Mirica

doi:10.1039/C3CC49387C

Dioxygen Activation by an Organometallic Pd(Ii) Precursor: Formation of a Pd(IV)–OH Complex and Its C–O Bond Formation Reactivity

Fengrui Qu
, Julia R. Khusnutdinova
, Nigam P. Rath
, Liviu M. Mirica

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Chemical Communications
Volume	50
DOIs	https://doi.org/10.1039/C3CC49387C
State	Published - Jan 1 2014

Disciplines

Organic Chemistry
Inorganic Chemistry
Chemistry

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10.1039/C3CC49387CLicense: Unspecified

Cite this

@article{a9dc126f4e0b49e2a1614fdfb3af112c,

title = "Dioxygen Activation by an Organometallic Pd(Ii) Precursor: Formation of a Pd(IV)–OH Complex and Its C–O Bond Formation Reactivity",

author = "Fengrui Qu and Khusnutdinova, \{Julia R.\} and Rath, \{Nigam P.\} and Mirica, \{Liviu M.\}",

note = "The complex (Me3tacn)PdII(CH2CMe2C6H4) is readily oxidized by O2 or H2O2 to yield the PdIV-OH complex [(Me3tacn)PdIV(OH)(CH2CMe2C6H4)]+. Thermolysis of this product leads to the selective C(sp2)-O reductive elimination of 2-tert-butylphenol, no C(sp3)-O elimination product being detected. This system represe Metal-Mediated Transformations of Small Molecules",

year = "2014",

month = jan,

day = "1",

doi = "10.1039/C3CC49387C",

language = "American English",

volume = "50",

journal = "Chemical Communications",

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TY - JOUR

T1 - Dioxygen Activation by an Organometallic Pd(Ii) Precursor: Formation of a Pd(IV)–OH Complex and Its C–O Bond Formation Reactivity

AU - Qu, Fengrui

AU - Khusnutdinova, Julia R.

AU - Rath, Nigam P.

AU - Mirica, Liviu M.

N1 - The complex (Me3tacn)PdII(CH2CMe2C6H4) is readily oxidized by O2 or H2O2 to yield the PdIV-OH complex [(Me3tacn)PdIV(OH)(CH2CMe2C6H4)]+. Thermolysis of this product leads to the selective C(sp2)-O reductive elimination of 2-tert-butylphenol, no C(sp3)-O elimination product being detected. This system represe Metal-Mediated Transformations of Small Molecules

PY - 2014/1/1

Y1 - 2014/1/1

UR - https://pubs.rsc.org/en/content/articlelanding/2014/cc/c3cc49387c#!

U2 - 10.1039/C3CC49387C

DO - 10.1039/C3CC49387C

M3 - Article

VL - 50

JO - Chemical Communications

JF - Chemical Communications

ER -

Dioxygen Activation by an Organometallic Pd(Ii) Precursor: Formation of a Pd(IV)–OH Complex and Its C–O Bond Formation Reactivity

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