Dioxidobis(2-Oxo-1,2-Dihydropyridin-3-Olato)­Molybdenum(VI)

Manoj Trivedi; Daya Shankar Pandey; Nigam P. Rath

doi:10.1107/S1600536808007782

Dioxidobis(2-Oxo-1,2-Dihydropyridin-3-Olato)Molybdenum(VI)

Manoj Trivedi, Daya Shankar Pandey, Nigam P. Rath

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [Mo(C5H4NO2)2O2], the MoVI atom exhibits a distorted octahedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other. The crystal structure contains intermolecular N-H...O hydrogen bonds, C-H...O contacts and face-to-face [pi]-[pi] stacking interactions with an interplanar separation of 3.25 (1) Å.

Original language	American English
Journal	Acta Crystallographica Section E-structure Reports Online
Volume	64
DOIs	https://doi.org/10.1107/S1600536808007782
State	Published - Apr 15 2008

Disciplines

Biochemistry
Bioinformatics
Chemistry
Inorganic Chemistry
Computer Sciences

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Cite this

@article{13f2300921d04dd7b46a0a95a9f799ed,

title = "Dioxidobis(2-Oxo-1,2-Dihydropyridin-3-Olato)Molybdenum(VI)",

abstract = " In the title compound, [Mo(C5H4NO2)2O2], the MoVI atom exhibits a distorted octahedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other. The crystal structure contains intermolecular N-H...O hydrogen bonds, C-H...O contacts and face-to-face [pi]-[pi] stacking interactions with an interplanar separation of 3.25 (1) {\AA}.",

author = "Manoj Trivedi and Pandey, {Daya Shankar} and Rath, {Nigam P.}",

year = "2008",

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language = "American English",

volume = "64",

journal = "Acta Crystallographica Section E-structure Reports Online",

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T1 - Dioxidobis(2-Oxo-1,2-Dihydropyridin-3-Olato)Molybdenum(VI)

AU - Trivedi, Manoj

AU - Pandey, Daya Shankar

AU - Rath, Nigam P.

PY - 2008/4/15

Y1 - 2008/4/15

N2 - In the title compound, [Mo(C5H4NO2)2O2], the MoVI atom exhibits a distorted octahedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other. The crystal structure contains intermolecular N-H...O hydrogen bonds, C-H...O contacts and face-to-face [pi]-[pi] stacking interactions with an interplanar separation of 3.25 (1) Å.

AB - In the title compound, [Mo(C5H4NO2)2O2], the MoVI atom exhibits a distorted octahedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are located trans to each other. The crystal structure contains intermolecular N-H...O hydrogen bonds, C-H...O contacts and face-to-face [pi]-[pi] stacking interactions with an interplanar separation of 3.25 (1) Å.

U2 - 10.1107/S1600536808007782

DO - 10.1107/S1600536808007782

M3 - Article

VL - 64

JO - Acta Crystallographica Section E-structure Reports Online

JF - Acta Crystallographica Section E-structure Reports Online

ER -