Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2)

Nigam P. Rath; Meghan Stouffer; Matthew K. Janssen; John R. Bleeke

doi:10.1107/S1600536811009305

Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2)

Nigam P. Rath, Meghan Stouffer, Matthew K. Janssen, John R. Bleeke

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

The asymmetric unit of the title crystal, [FeCl2(C3H9P)3(CO)]·[FeCl2(C3H9P)2(CO)2]·2C4H8O, contains half molecules of the two closely related FeII complexes lying on mirror planes and a tetrahydrofuran solvent molecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex molecules, a distorted octahedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C-H...O interactions are observed in the crystal structure.

Original language	American English
Journal	Acta Crystallographica Section E-structure Reports Online
Volume	67
DOIs	https://doi.org/10.1107/S1600536811009305
State	Published - Apr 15 2011

Disciplines

Computer Sciences
Biochemistry
Chemistry

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Cite this

@article{93b7ea7956554976861edd173525ac29,

title = "Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2)",

abstract = " The asymmetric unit of the title crystal, [FeCl2(C3H9P)3(CO)]·[FeCl2(C3H9P)2(CO)2]·2C4H8O, contains half molecules of the two closely related FeII complexes lying on mirror planes and a tetrahydrofuran solvent molecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex molecules, a distorted octahedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C-H...O interactions are observed in the crystal structure.",

author = "Rath, {Nigam P.} and Meghan Stouffer and Janssen, {Matthew K.} and Bleeke, {John R.}",

year = "2011",

month = apr,

day = "15",

doi = "10.1107/S1600536811009305",

language = "American English",

volume = "67",

journal = "Acta Crystallographica Section E-structure Reports Online",

}

TY - JOUR

T1 - Dicarbonyldichloridobis(Trimethylphosphane)Iron(Ii)–Carbonyldichloridotris(Trimethylphosphane)Iron(Ii)–Tetrahydrofuran (1/1/2)

AU - Rath, Nigam P.

AU - Stouffer, Meghan

AU - Janssen, Matthew K.

AU - Bleeke, John R.

PY - 2011/4/15

Y1 - 2011/4/15

N2 - The asymmetric unit of the title crystal, [FeCl2(C3H9P)3(CO)]·[FeCl2(C3H9P)2(CO)2]·2C4H8O, contains half molecules of the two closely related FeII complexes lying on mirror planes and a tetrahydrofuran solvent molecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex molecules, a distorted octahedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C-H...O interactions are observed in the crystal structure.

AB - The asymmetric unit of the title crystal, [FeCl2(C3H9P)3(CO)]·[FeCl2(C3H9P)2(CO)2]·2C4H8O, contains half molecules of the two closely related FeII complexes lying on mirror planes and a tetrahydrofuran solvent molecule, one C atom of which is disordered over two sets of sites with site occupancy factors 0.633 (9) and 0.367 (9). In both FeII complex molecules, a distorted octahedral coordination geometry has been observed around the Fe atoms. Weak intermolecular C-H...O interactions are observed in the crystal structure.

U2 - 10.1107/S1600536811009305

DO - 10.1107/S1600536811009305

M3 - Article

VL - 67

JO - Acta Crystallographica Section E-structure Reports Online

JF - Acta Crystallographica Section E-structure Reports Online

ER -