(d438;) and (d44d;)-1,4-Diphenyl-2-(2-Phenyl-1d43b;-Benzo[d451;]Imidazol-1- Yl)But-2-Ene-1,4-Dione

Sarfaraz Ahmed; Niyaz A. Mir; Tariq A. Shah; Waseem Raza; M. Muneer; Nigam P. Rath

doi:10.1155/2014/207646

(d438;) and (d44d;)-1,4-Diphenyl-2-(2-Phenyl-1d43b;-Benzo[d451;]Imidazol-1- Yl)But-2-Ene-1,4-Dione

Sarfaraz Ahmed, Niyaz A. Mir, Tariq A. Shah, Waseem Raza, M. Muneer, Nigam P. Rath

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound C 29 H 20 N 2 O 2 adopts and geometry about olefinic C14–C22 bond, where the benzoyl group at C22 and benzimidazole group at C14 lie on the opposite sides and on the same side across the olefinic bond, respectively. In configuration the phenyl groups of both benzoyl moieties are almost perpendicular to benzimidazole ring while the phenyl of benzimidazole at C7 is oriented at an angle of 30.76 (5)° to the mean plane of the benzimidazole ring. On the other hand in configuration the phenyl group at C7 of benzimidazole ring is oriented at an angle of 38.44 (7)° to the mean plane of the benzimidazole ring while the phenyl rings of benzoyl moieties at C15 and C23 lie at an angle of 16.07 (9)° and 40.29 (6)°, respectively, to the mean plane of the benzimidazole ring. The observed bond distances and bond angles fall within the normal accepted range of values.

Original language	American English
Journal	Journal of Crystallography
Volume	2014
DOIs	https://doi.org/10.1155/2014/207646
State	Published - May 27 2014

Disciplines

Biochemistry, Biophysics, and Structural Biology
Chemistry
Organic Chemistry

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(𝐸) and (𝑍)-1,4-Diphenyl-2-(2-Phenyl-1𝐻-Benzo[𝑑]Imidazol-1- Yl)But-2-Ene-1,4-Dione.pdfFinal published version, 2.93 MBLicense: Unspecified

Cite this

@article{7b2765628a5b4d3c88e0aa8507ff5fd6,

title = "(d438;) and (d44d;)-1,4-Diphenyl-2-(2-Phenyl-1d43b;-Benzo[d451;]Imidazol-1- Yl)But-2-Ene-1,4-Dione",

abstract = " The title compound C 29 H 20 N 2 O 2 adopts and geometry about olefinic C14–C22 bond, where the benzoyl group at C22 and benzimidazole group at C14 lie on the opposite sides and on the same side across the olefinic bond, respectively. In configuration the phenyl groups of both benzoyl moieties are almost perpendicular to benzimidazole ring while the phenyl of benzimidazole at C7 is oriented at an angle of 30.76 (5)° to the mean plane of the benzimidazole ring. On the other hand in configuration the phenyl group at C7 of benzimidazole ring is oriented at an angle of 38.44 (7)° to the mean plane of the benzimidazole ring while the phenyl rings of benzoyl moieties at C15 and C23 lie at an angle of 16.07 (9)° and 40.29 (6)°, respectively, to the mean plane of the benzimidazole ring. The observed bond distances and bond angles fall within the normal accepted range of values. ",

author = "Sarfaraz Ahmed and Mir, {Niyaz A.} and Shah, {Tariq A.} and Waseem Raza and M. Muneer and Rath, {Nigam P.}",

year = "2014",

month = may,

day = "27",

doi = "10.1155/2014/207646",

language = "American English",

volume = "2014",

journal = "Journal of Crystallography",

}

TY - JOUR

T1 - (d438;) and (d44d;)-1,4-Diphenyl-2-(2-Phenyl-1d43b;-Benzo[d451;]Imidazol-1- Yl)But-2-Ene-1,4-Dione

AU - Ahmed, Sarfaraz

AU - Mir, Niyaz A.

AU - Shah, Tariq A.

AU - Raza, Waseem

AU - Muneer, M.

AU - Rath, Nigam P.

PY - 2014/5/27

Y1 - 2014/5/27

N2 - The title compound C 29 H 20 N 2 O 2 adopts and geometry about olefinic C14–C22 bond, where the benzoyl group at C22 and benzimidazole group at C14 lie on the opposite sides and on the same side across the olefinic bond, respectively. In configuration the phenyl groups of both benzoyl moieties are almost perpendicular to benzimidazole ring while the phenyl of benzimidazole at C7 is oriented at an angle of 30.76 (5)° to the mean plane of the benzimidazole ring. On the other hand in configuration the phenyl group at C7 of benzimidazole ring is oriented at an angle of 38.44 (7)° to the mean plane of the benzimidazole ring while the phenyl rings of benzoyl moieties at C15 and C23 lie at an angle of 16.07 (9)° and 40.29 (6)°, respectively, to the mean plane of the benzimidazole ring. The observed bond distances and bond angles fall within the normal accepted range of values.

AB - The title compound C 29 H 20 N 2 O 2 adopts and geometry about olefinic C14–C22 bond, where the benzoyl group at C22 and benzimidazole group at C14 lie on the opposite sides and on the same side across the olefinic bond, respectively. In configuration the phenyl groups of both benzoyl moieties are almost perpendicular to benzimidazole ring while the phenyl of benzimidazole at C7 is oriented at an angle of 30.76 (5)° to the mean plane of the benzimidazole ring. On the other hand in configuration the phenyl group at C7 of benzimidazole ring is oriented at an angle of 38.44 (7)° to the mean plane of the benzimidazole ring while the phenyl rings of benzoyl moieties at C15 and C23 lie at an angle of 16.07 (9)° and 40.29 (6)°, respectively, to the mean plane of the benzimidazole ring. The observed bond distances and bond angles fall within the normal accepted range of values.

U2 - 10.1155/2014/207646

DO - 10.1155/2014/207646

M3 - Article

VL - 2014

JO - Journal of Crystallography

JF - Journal of Crystallography

ER -