[(CO)H(PPh3)2-Arachno-OsB3H8]

Nigam Rath; J. Bould; L. Barton

doi:10.1107/S0108270195017239

[(CO)H(PPh3)2-Arachno-OsB3H8]

Nigam Rath, J. Bould, L. Barton

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

A single-crystal X-ray diffraction study of the species 2-carbonyl2-hydrido-trans-2,2-bis(triphenylphosphine)-2-osma-arachno-tetraborane confirms the structure as a tetraborane(10) butterfly with a trans-[(CO)H(PPh3)2Os] group replacing a BH2 group at a wing-tip or 2-position. It is compared with the previously reported ruthenaborane analogue (CO)H(PPh3)2-arachno-RuB3H8.

Original language	American English
Journal	Acta Crystallographica Section C: Crystal Structure Communications
DOIs	https://doi.org/10.1107/S0108270195017239
State	Published - 1996

Disciplines

Chemistry

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Cite this

@article{2dcaacc2b1fa416db1f6608fec02c945,

title = "[(CO)H(PPh3)2-Arachno-OsB3H8]",

abstract = " A single-crystal X-ray diffraction study of the species 2-carbonyl2-hydrido-trans-2,2-bis(triphenylphosphine)-2-osma-arachno-tetraborane confirms the structure as a tetraborane(10) butterfly with a trans-[(CO)H(PPh3)2Os] group replacing a BH2 group at a wing-tip or 2-position. It is compared with the previously reported ruthenaborane analogue (CO)H(PPh3)2-arachno-RuB3H8.",

author = "Nigam Rath and J. Bould and L. Barton",

year = "1996",

doi = "10.1107/S0108270195017239",

language = "American English",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

}

TY - JOUR

T1 - [(CO)H(PPh3)2-Arachno-OsB3H8]

AU - Rath, Nigam

AU - Bould, J.

AU - Barton, L.

PY - 1996

Y1 - 1996

N2 - A single-crystal X-ray diffraction study of the species 2-carbonyl2-hydrido-trans-2,2-bis(triphenylphosphine)-2-osma-arachno-tetraborane confirms the structure as a tetraborane(10) butterfly with a trans-[(CO)H(PPh3)2Os] group replacing a BH2 group at a wing-tip or 2-position. It is compared with the previously reported ruthenaborane analogue (CO)H(PPh3)2-arachno-RuB3H8.

AB - A single-crystal X-ray diffraction study of the species 2-carbonyl2-hydrido-trans-2,2-bis(triphenylphosphine)-2-osma-arachno-tetraborane confirms the structure as a tetraborane(10) butterfly with a trans-[(CO)H(PPh3)2Os] group replacing a BH2 group at a wing-tip or 2-position. It is compared with the previously reported ruthenaborane analogue (CO)H(PPh3)2-arachno-RuB3H8.

U2 - 10.1107/S0108270195017239

DO - 10.1107/S0108270195017239

M3 - Article

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -