Bromine kinetic isotope effects: insight into Grignard reagent formation

Lukasz Szatkowski; Agnieszka Dybala-Defratyka; Charlie Batarseh; Jochanan Blum; Ludwik Halicz; Faina Gelman

doi:10.1039/C3NJ00197K

Bromine kinetic isotope effects: insight into Grignard reagent formation

Lukasz Szatkowski
, Agnieszka Dybala-Defratyka
, Charlie Batarseh
, Jochanan Blum
, Ludwik Halicz
, Faina Gelman

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Abstract

The study focuses on the determination of bromine kinetic isotope effects (Br-KIEs) on Grignard reagent formation applying compound specific bromine isotope analysis. Clear difference between the Br-KIE values for aromatic and aliphatic bromides was observed. The measured Br-KIE values were found to be in a good agreement with the theoretical predictions.

Original language	American English
Journal	New Journal of Chemistry
DOIs	https://doi.org/10.1039/C3NJ00197K
State	Published - 2013

Disciplines

Chemistry

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10.1039/C3NJ00197KLicense: Unspecified

Cite this

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abstract = " The study focuses on the determination of bromine kinetic isotope effects (Br-KIEs) on Grignard reagent formation applying compound specific bromine isotope analysis. Clear difference between the Br-KIE values for aromatic and aliphatic bromides was observed. The measured Br-KIE values were found to be in a good agreement with the theoretical predictions. ",

author = "Lukasz Szatkowski and Agnieszka Dybala-Defratyka and Charlie Batarseh and Jochanan Blum and Ludwik Halicz and Faina Gelman",

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language = "American English",

journal = "New Journal of Chemistry",

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T1 - Bromine kinetic isotope effects: insight into Grignard reagent formation

AU - Szatkowski, Lukasz

AU - Dybala-Defratyka, Agnieszka

AU - Batarseh, Charlie

AU - Blum, Jochanan

AU - Halicz, Ludwik

AU - Gelman, Faina

N1 - The study focuses on the determination of bromine kinetic isotope effects (Br-KIEs) on Grignard reagent formation applying compound specific bromine isotope analysis. Clear difference between the Br-KIE values for aromatic and aliphatic bromides was observed. The measured Br-KIE values were found to be in a

PY - 2013

Y1 - 2013

N2 - The study focuses on the determination of bromine kinetic isotope effects (Br-KIEs) on Grignard reagent formation applying compound specific bromine isotope analysis. Clear difference between the Br-KIE values for aromatic and aliphatic bromides was observed. The measured Br-KIE values were found to be in a good agreement with the theoretical predictions.

AB - The study focuses on the determination of bromine kinetic isotope effects (Br-KIEs) on Grignard reagent formation applying compound specific bromine isotope analysis. Clear difference between the Br-KIE values for aromatic and aliphatic bromides was observed. The measured Br-KIE values were found to be in a good agreement with the theoretical predictions.

UR - https://doi.org/10.1039/C3NJ00197K

U2 - 10.1039/C3NJ00197K

DO - 10.1039/C3NJ00197K

M3 - Article

JO - New Journal of Chemistry

JF - New Journal of Chemistry

ER -

Bromine kinetic isotope effects: insight into Grignard reagent formation

Abstract

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