Bromine kinetic isotope effects: insight into Grignard reagent formation

Lukasz Szatkowski, Agnieszka Dybala-Defratyka, Charlie Batarseh, Jochanan Blum, Ludwik Halicz, Faina Gelman

Research output: Contribution to journalArticlepeer-review

Abstract

The study focuses on the determination of bromine kinetic isotope effects (Br-KIEs) on Grignard reagent formation applying compound specific bromine isotope analysis. Clear difference between the Br-KIE values for aromatic and aliphatic bromides was observed. The measured Br-KIE values were found to be in a good agreement with the theoretical predictions.

Original languageAmerican English
JournalNew Journal of Chemistry
DOIs
StatePublished - 2013

Disciplines

  • Chemistry

Cite this