A Thiocyanato-Bridged Copper(I) Cubane Complex and Its Application in Palladium-Catalyzed Sonogashira Coupling of Aryl Halides

Manoj Trivedi; Gurmeet Singh; Abhinav Kumar; Nigam P. Rath

doi:10.1039/c3dt51196k

A Thiocyanato-Bridged Copper(I) Cubane Complex and Its Application in Palladium-Catalyzed Sonogashira Coupling of Aryl Halides

Manoj Trivedi
, Gurmeet Singh
, Abhinav Kumar
, Nigam P. Rath

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Dalton Transactions
Volume	42
DOIs	https://doi.org/10.1039/c3dt51196k
State	Published - Jan 1 2013

Disciplines

Chemistry
Inorganic Chemistry

Access to Document

10.1039/c3dt51196kLicense: Unspecified

Cite this

@article{66c28213fa6e4980b58b72d6c373866d,

title = "A Thiocyanato-Bridged Copper(I) Cubane Complex and Its Application in Palladium-Catalyzed Sonogashira Coupling of Aryl Halides",

author = "Manoj Trivedi and Gurmeet Singh and Abhinav Kumar and Rath, \{Nigam P.\}",

note = "Reaction of copper(i) thiocyanate with 1,1′-bis(di-tert-butylphosphino) ferrocene (dtbpf) in a 2 : 1 molar ratio in DCM-MeOH (50 : 50 V/V) afforded a tetranuclear copper(i) complex [Cu4(μ3-SCN)4(κ1-P,P-dtbpf)2] (1) with a cubane-like structure. Complex 1 was shown to be an efficient catalyst in comparison to",

year = "2013",

month = jan,

day = "1",

doi = "10.1039/c3dt51196k",

language = "American English",

volume = "42",

journal = "Dalton Transactions",

}

TY - JOUR

T1 - A Thiocyanato-Bridged Copper(I) Cubane Complex and Its Application in Palladium-Catalyzed Sonogashira Coupling of Aryl Halides

AU - Trivedi, Manoj

AU - Singh, Gurmeet

AU - Kumar, Abhinav

AU - Rath, Nigam P.

N1 - Reaction of copper(i) thiocyanate with 1,1′-bis(di-tert-butylphosphino) ferrocene (dtbpf) in a 2 : 1 molar ratio in DCM-MeOH (50 : 50 V/V) afforded a tetranuclear copper(i) complex [Cu4(μ3-SCN)4(κ1-P,P-dtbpf)2] (1) with a cubane-like structure. Complex 1 was shown to be an efficient catalyst in comparison to

PY - 2013/1/1

Y1 - 2013/1/1

UR - http://pubs.rsc.org/en/Content/ArticleLanding/DT/2013/C3DT51196K

U2 - 10.1039/c3dt51196k

DO - 10.1039/c3dt51196k

M3 - Article

VL - 42

JO - Dalton Transactions

JF - Dalton Transactions

ER -

A Thiocyanato-Bridged Copper(I) Cubane Complex and Its Application in Palladium-Catalyzed Sonogashira Coupling of Aryl Halides

Disciplines

Access to Document

Other files and links

Cite this