TY - JOUR
T1 - A Stable Hydrogen-Bonded Coordination Network with Removable Guests
AU - Hogan, Greg A.
AU - Rath, Nigam P.
AU - Beatty, Alicia M.
N1 - Zinc(II) coordination complexes, each having two linearly oriented peripheral carboxylate units, combine with 3,3′-dimethylbenzidene pillars to create channeled structures that host small organic guests. The porous solids reported here are connected solely via strong, charge-assisted hydrogen bonds and contain guests that vary in size, shape, and degree of hydrophobicity.
PY - 2011/9/7
Y1 - 2011/9/7
N2 - Zinc(II) coordination complexes, each having two linearly oriented peripheral carboxylate units, combine with 3,3′-dimethylbenzidene pillars to create channeled structures that host small organic guests. The porous solids reported here are connected solely via strong, charge-assisted hydrogen bonds and contain guests that vary in size, shape, and degree of hydrophobicity. The hydrogen-bonded framework is maintained upon guest loss, under vacuum and up to ∼200 °C. The strength and flexibility of these frameworks make them ideal candidates for molecular storage, separations, guest exchange, and guest transport.
AB - Zinc(II) coordination complexes, each having two linearly oriented peripheral carboxylate units, combine with 3,3′-dimethylbenzidene pillars to create channeled structures that host small organic guests. The porous solids reported here are connected solely via strong, charge-assisted hydrogen bonds and contain guests that vary in size, shape, and degree of hydrophobicity. The hydrogen-bonded framework is maintained upon guest loss, under vacuum and up to ∼200 °C. The strength and flexibility of these frameworks make them ideal candidates for molecular storage, separations, guest exchange, and guest transport.
UR - http://pubs.acs.org/doi/abs/10.1021/cg200793f?volume=11
UR - https://pubs.acs.org/doi/abs/10.1021/cg200793f
U2 - 10.1021/cg200793f
DO - 10.1021/cg200793f
M3 - Article
VL - 11
JO - Crystal Growth Design
JF - Crystal Growth Design
ER -