A Cyano-Bridged Copper(II)–Copper(I) Mixed-Valence Coordination Polymer as a Source of Copper Oxide Nanoparticles with Catalytic Activity in C–N, C–O and C–S Cross-Coupling Reactions

Manoj Trivedi; Sanjeev kumar Ujjain; Raj Kishore Sharma; Gurmeet Singh; Abhinav Kumar; Nigam P. Rath

doi:10.1039/C4NJ00829D

A Cyano-Bridged Copper(II)–Copper(I) Mixed-Valence Coordination Polymer as a Source of Copper Oxide Nanoparticles with Catalytic Activity in C–N, C–O and C–S Cross-Coupling Reactions

Manoj Trivedi, Sanjeev kumar Ujjain, Raj Kishore Sharma, Gurmeet Singh, Abhinav Kumar, Nigam P. Rath

University of Missouri-St. Louis

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Original language	American English
Journal	New Journal of Chemistry
Volume	38
DOIs	https://doi.org/10.1039/C4NJ00829D
State	Published - Jan 1 2014

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Organic Chemistry
Inorganic Chemistry

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A Cyano-Bridged Copper(II)–Copper(I) Mixed-Valence Coordination Polymer as a Source of Copper Oxide Nanoparticles with Catalytic Activity in C–N, C–O and C–S Cross-Coupling Reactions. / Trivedi, Manoj; Ujjain, Sanjeev kumar; Sharma, Raj Kishore et al.
In: New Journal of Chemistry, Vol. 38, 01.01.2014.

Research output: Contribution to journal › Article › peer-review

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title = "A Cyano-Bridged Copper(II)–Copper(I) Mixed-Valence Coordination Polymer as a Source of Copper Oxide Nanoparticles with Catalytic Activity in C–N, C–O and C–S Cross-Coupling Reactions",

author = "Manoj Trivedi and Ujjain, {Sanjeev kumar} and Sharma, {Raj Kishore} and Gurmeet Singh and Abhinav Kumar and Rath, {Nigam P.}",

note = "A cyano-bridged copper( II)-copper( I) mixed valence polymer, namely {[Cu(CN)(CHN)]} ( 1), was synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, differential scanning calorimetric analysis, and single crystal X-ray crystallography. Single crystal X-ray studies show that the coordination polymer 1 is linked by the cyanide anions with μ-1κN:2κC bridging modes to the copper centers, generating a two-dimensional (2D) layered network.",

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T1 - A Cyano-Bridged Copper(II)–Copper(I) Mixed-Valence Coordination Polymer as a Source of Copper Oxide Nanoparticles with Catalytic Activity in C–N, C–O and C–S Cross-Coupling Reactions

AU - Trivedi, Manoj

AU - Ujjain, Sanjeev kumar

AU - Sharma, Raj Kishore

AU - Singh, Gurmeet

AU - Kumar, Abhinav

AU - Rath, Nigam P.

N1 - A cyano-bridged copper( II)-copper( I) mixed valence polymer, namely {[Cu(CN)(CHN)]} ( 1), was synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, differential scanning calorimetric analysis, and single crystal X-ray crystallography. Single crystal X-ray studies show that the coordination polymer 1 is linked by the cyanide anions with μ-1κN:2κC bridging modes to the copper centers, generating a two-dimensional (2D) layered network.

PY - 2014/1/1

Y1 - 2014/1/1

UR - http://pubs.rsc.org/en/content/articlelanding/2014/nj/c4nj00829d#!

U2 - 10.1039/C4NJ00829D

DO - 10.1039/C4NJ00829D

M3 - Article

VL - 38

JO - New Journal of Chemistry

JF - New Journal of Chemistry

ER -

A Cyano-Bridged Copper(II)–Copper(I) Mixed-Valence Coordination Polymer as a Source of Copper Oxide Nanoparticles with Catalytic Activity in C–N, C–O and C–S Cross-Coupling Reactions

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