A Cyano-Based Octanuclear {FeIII4NiII4} Single-Molecule Magnet

Yuanzhu Zhang; Uma Prasad Mallik; Nigam Rath; Gordon T. Yee; Rodolphe Clérac; Rodolphe Clérac; Stephen M. Holmes

doi:10.1039/C0CC00317D

A Cyano-Based Octanuclear {FeIII4NiII4} Single-Molecule Magnet

Yuanzhu Zhang, Uma Prasad Mallik, Nigam Rath, Gordon T. Yee, Rodolphe Clérac, Rodolphe Clérac, Stephen M. Holmes

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Chemical Communications
Volume	46
DOIs	https://doi.org/10.1039/C0CC00317D
State	Published - Jan 1 2010

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Atomic, Molecular and Optical Physics

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10.1039/C0CC00317DLicense: Unspecified

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@article{c6ebb39fef1e475c9c355ba61edd8de5,

title = "A Cyano-Based Octanuclear \{FeIII4NiII4\} Single-Molecule Magnet",

author = "Yuanzhu Zhang and Mallik, \{Uma Prasad\} and Nigam Rath and Yee, \{Gordon T.\} and Rodolphe Cl{\'e}rac and Rodolphe Cl{\'e}rac and Holmes, \{Stephen M.\}",

note = "A new low symmetry octanuclear cyano-based \{FeIII4NiII4\} single-molecule magnet (SMM) is described. This SMM exhibits the highest energy barrier (Δ/kB ≈ 33 K) for magnetization reversal seen for any first-row cyanide-based complex. The importance of anisotropy axes alignment and their impact on SMM propertie",

year = "2010",

month = jan,

day = "1",

doi = "10.1039/C0CC00317D",

language = "American English",

volume = "46",

journal = "Chemical Communications",

}

TY - JOUR

T1 - A Cyano-Based Octanuclear {FeIII4NiII4} Single-Molecule Magnet

AU - Zhang, Yuanzhu

AU - Mallik, Uma Prasad

AU - Rath, Nigam

AU - Yee, Gordon T.

AU - Clérac, Rodolphe

AU - Holmes, Stephen M.

N1 - A new low symmetry octanuclear cyano-based {FeIII4NiII4} single-molecule magnet (SMM) is described. This SMM exhibits the highest energy barrier (Δ/kB ≈ 33 K) for magnetization reversal seen for any first-row cyanide-based complex. The importance of anisotropy axes alignment and their impact on SMM propertie

PY - 2010/1/1

Y1 - 2010/1/1

UR - http://pubs.rsc.org/en/content/articlelanding/2010/cc/c0cc00317d

UR - http://pubs.rsc.org/en/content/articlelanding/2010/cc/c0cc00317d#!

U2 - 10.1039/C0CC00317D

DO - 10.1039/C0CC00317D

M3 - Article

VL - 46

JO - Chemical Communications

JF - Chemical Communications

ER -

A Cyano-Based Octanuclear {FeIII4NiII4} Single-Molecule Magnet

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