A Comparative Study of Glycosyl Thioimidates as Building Blocks for Chemical Glycosylation

Sneha C. Ranade; Scott J. Hasty; Alexei V. Demchenko

doi:10.1080/07328303.2013.826670

A Comparative Study of Glycosyl Thioimidates as Building Blocks for Chemical Glycosylation

Sneha C. Ranade
, Scott J. Hasty
, Alexei V. Demchenko

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of Carbohydrate Chemistry
Volume	32
DOIs	https://doi.org/10.1080/07328303.2013.826670
State	Published - Jul 24 2013

Disciplines

Biochemistry
Organic Chemistry

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10.1080/07328303.2013.826670License: Unspecified

Cite this

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title = "A Comparative Study of Glycosyl Thioimidates as Building Blocks for Chemical Glycosylation",

author = "Ranade, \{Sneha C.\} and Hasty, \{Scott J.\} and Demchenko, \{Alexei V.\}",

note = "Our results indicate that the reactivity and the activation profile of thioimidate glycosyl donors vary significantly depending on the endocyclic heteroatom (N,O,S). Reactivity diminishes in accordance with the following sequence: O > S > N; and this trend stands for a majority of promoters tested.",

year = "2013",

month = jul,

day = "24",

doi = "10.1080/07328303.2013.826670",

language = "American English",

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journal = "Journal of Carbohydrate Chemistry",

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T1 - A Comparative Study of Glycosyl Thioimidates as Building Blocks for Chemical Glycosylation

AU - Ranade, Sneha C.

AU - Hasty, Scott J.

AU - Demchenko, Alexei V.

N1 - Our results indicate that the reactivity and the activation profile of thioimidate glycosyl donors vary significantly depending on the endocyclic heteroatom (N,O,S). Reactivity diminishes in accordance with the following sequence: O > S > N; and this trend stands for a majority of promoters tested.

PY - 2013/7/24

Y1 - 2013/7/24

UR - http://www.tandfonline.com/doi/full/10.1080/07328303.2013.826670

U2 - 10.1080/07328303.2013.826670

DO - 10.1080/07328303.2013.826670

M3 - Article

VL - 32

JO - Journal of Carbohydrate Chemistry

JF - Journal of Carbohydrate Chemistry

ER -

A Comparative Study of Glycosyl Thioimidates as Building Blocks for Chemical Glycosylation

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