1,1′-Bis(Di-Tert-Butylphosphino)Ferrocene Copper(I) Complex Catalyzed C–H Activation and Carboxylation of Terminal Alkynes

Manoj Trivedi; Gurmeet Singh; Abhinav Kumar; Nigam P. Rath

doi:10.1039/C5DT03794H

1,1′-Bis(Di-Tert-Butylphosphino)Ferrocene Copper(I) Complex Catalyzed C–H Activation and Carboxylation of Terminal Alkynes

Manoj Trivedi, Gurmeet Singh, Abhinav Kumar, Nigam P. Rath

University of Missouri-St. Louis

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Dalton Transactions
Volume	44
DOIs	https://doi.org/10.1039/C5DT03794H
State	Published - Jan 1 2015

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Chemistry
Inorganic Chemistry

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title = "1,1′-Bis(Di-Tert-Butylphosphino)Ferrocene Copper(I) Complex Catalyzed C–H Activation and Carboxylation of Terminal Alkynes",

author = "Manoj Trivedi and Gurmeet Singh and Abhinav Kumar and Rath, {Nigam P.}",

note = "Four copper( I) complexes, [CuBr(dtbpf)] ( 1), [CuI(dtbpf)] ( 2), [Cu(μ-I)(μ-I)(μ-dtbpf)] ( 3) and [Cu(μ-I)(μ-dtbpf)]·2CHCN ( 4), were prepared using CuX (X = Br, I) and 1,1′-bis(di- tert-butylphosphino)ferrocene (dtbpf). These complexes have been characterized by elemental analyses, IR, H and P NMR, ESI-MS and electronic absorption spectroscopy.",

year = "2015",

month = jan,

day = "1",

doi = "10.1039/C5DT03794H",

language = "American English",

volume = "44",

journal = "Dalton Transactions",

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TY - JOUR

T1 - 1,1′-Bis(Di-Tert-Butylphosphino)Ferrocene Copper(I) Complex Catalyzed C–H Activation and Carboxylation of Terminal Alkynes

AU - Trivedi, Manoj

AU - Singh, Gurmeet

AU - Kumar, Abhinav

AU - Rath, Nigam P.

N1 - Four copper( I) complexes, [CuBr(dtbpf)] ( 1), [CuI(dtbpf)] ( 2), [Cu(μ-I)(μ-I)(μ-dtbpf)] ( 3) and [Cu(μ-I)(μ-dtbpf)]·2CHCN ( 4), were prepared using CuX (X = Br, I) and 1,1′-bis(di- tert-butylphosphino)ferrocene (dtbpf). These complexes have been characterized by elemental analyses, IR, H and P NMR, ESI-MS and electronic absorption spectroscopy.

PY - 2015/1/1

Y1 - 2015/1/1

UR - http://pubs.rsc.org/en/content/articlelanding/2015/dt/c5dt03794h

U2 - 10.1039/C5DT03794H

DO - 10.1039/C5DT03794H

M3 - Article

VL - 44

JO - Dalton Transactions

JF - Dalton Transactions

ER -

1,1′-Bis(Di-Tert-Butylphosphino)Ferrocene Copper(I) Complex Catalyzed C–H Activation and Carboxylation of Terminal Alkynes

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